Thermodynamic calculation of the melting diagram of the Mg-MgO-B system at a pressure of 2 GPa View Full Text


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Article Info

DATE

2009-04

AUTHORS

V. Z. Turkevich, A. V. Kozyrev

ABSTRACT

Phase equilibria with the participation of a liquid phase in the Mg-MgO-B ternary system at 2 GPa have been calculated in the framework of model approximations of the phenomenological thermodynamics. The melting diagram of the system is characterized by five nonvariant four-phase equilibria, three of which are peritectic and two eutectic ones. The region of the primary crystallization of magnesium diboride MgB2 in the diagram is near the Mg-B binary system region and as the oxygen concentration increases, disappears and is replaced by the crystallization regions of MgO and MgB4 at the point of peritectic equilibrium L + MgB2 ⇄ MgO + MgB4 (1345 K, 68 at % B, 10 at % O). More... »

PAGES

78-81

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.3103/s1063457609020026

DOI

http://dx.doi.org/10.3103/s1063457609020026

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1005661968


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