On the problem of the phase relations in the B-BN system at high pressures and temperatures View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-02

AUTHORS

V. L. Solozhenko, O. O. Kurakevych, V. Z. Turkevich, D. V. Turkevich

ABSTRACT

Phase relations and chemical interaction in the B-BN system have been studied in situ using X-ray diffraction with synchrotron radiation at pressures to 5.3 GPa and temperatures to 2700 K. The results obtained have been used for the thermodynamic analysis of this system and for the construction of its phase diagram at 5 GPa. The values of thermodynamic functions of the phases competing in the B-BN system at high pressures and temperatures have been calculated in the framework of phenomenological models, unknown parameters of which have been found from the experimental data. It has been shown that only one thermodynamically stable boron subnitride (rhombohedral B13N2) exists in the system. It melts incongruently and forms an eutectic equilibrium with boron. More... »

PAGES

1-6

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.3103/s1063457609010018

DOI

http://dx.doi.org/10.3103/s1063457609010018

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1041024525


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