Local environment of 119Sn4+ probe ions in the bulk and on the surfaces of substituted chromites with perovskite-type structure Y1–xCaxCrO3 View Full Text


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Article Info

DATE

2015-08

AUTHORS

P. B. Fabrichnyi, M. I. Afanasov, E. M. Mezhuev, A. Wattiaux, C. Labrugère, C. Delmas

ABSTRACT

A specific feature of the Mössbauer spectra of 119Sn in Y1–xCaxCrO3 samples containing 0.3 at % Sn4+ in the bulk of crystallites is an extra sextet component corresponding to hyperfine field H(119Sn) = 65 kOe at 4.2 K. This effect is explained by the formation of Sn4+ impurity associates in the chromium sublattice. A drastic weakening in spin polarization is observed for the Sn4+ ions in surface sites, but is found not to be related to the presence of heterovalent Ca2+ ions. More... »

PAGES

1046-1050

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.3103/s1062873815080055

DOI

http://dx.doi.org/10.3103/s1062873815080055

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1036470753


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