Hyperfine interactions, charge compensation mechanisms, and the distribution of tin dopant cations in rare-earth orthochromites RCrO3 (R = Sm, Eu, ... View Full Text


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Article Info

DATE

2013-06

AUTHORS

P. B. Fabritchnyi, M. I. Afanasov, E. M. Mezhuev, R. A. Astashkin, A. Wattiaux, S. Bordère, C. Labrugère, C. Delmas

ABSTRACT

The reduction in the squared cosine of angle θ of the Cr-O-Cr bond in the Sm-Ho series in samples containing Sn4+ ions in the Cr3+ position in the crystallite bulk is accompanied by a linear increase in hyperfine field HT→0 K at 119Sn nuclei. Upon annealing in H2, tin attains oxidation state +2 occupying the Cr3+ and R3+ positions on the surfaces of particles. Mössbauer measurements in situ at 100 K do not reveal the spin polarization of Sn2+, but this polarization does manifest itself for part of the daughter Sn4+ ions formed when samples come into contact with air. More... »

PAGES

745-751

Identifiers

URI

http://scigraph.springernature.com/pub.10.3103/s1062873813060117

DOI

http://dx.doi.org/10.3103/s1062873813060117

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1016079563


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