Effect of local cationic environment on the valence state of 119Sn probe atoms on the surface of antiferromagnet MnTiO3 with ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-09

AUTHORS

M. V. Korolenko, P. B. Fabrichnyi, M. I. Afanasov, I. M. Buntseva

ABSTRACT

Annealing in argon of MnTiO3 impregnated with a SnCl4 solution leads to the distribution of Sn4+ ions over sites with different cationic environments in the surface layers of crystallites. The chemical behavior of Sn4+ ions emerging on the surface upon subsequent annealing in hydrogen depends on the tendency of the neighboring cations to retain the octahedral coordination by O2− anions. The absence of spin polarization of the Sn2+ cations formed on the surface shows that their specific valence state is stabilized by the nearby Ti4+ cations. More... »

PAGES

1236-1239

Identifiers

URI

http://scigraph.springernature.com/pub.10.3103/s1062873807090092

DOI

http://dx.doi.org/10.3103/s1062873807090092

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1002430171


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