Metal-Doped MgB2 by Thermal Explosion: A TRXRD Study View Full Text


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Article Info

DATE

2018-01

AUTHORS

A. Yu. Potanin, D. Yu. Kovalev, Yu. S. Pogozhev, N. Yu. Khomenko

ABSTRACT

The work aimed at preparation of the MgB2 doped with alloying metals (Al, Cu, Ag, Zn) by SHS in a mode of thermal explosion. The measured combustion temperatures fell within the range 940–1030°С. Detailed XRD analysis has shown that, among other selected metals, it is solely Al that can enter the MgB2 lattice. According to time-resolved XRD results, the formation of final product (Mg, Al)B2 in the Mg–Al–B system involved no intermediate phases. But in the Mg–Cu–B system, the volume reaction additionally yielded MgB4, Cu2Mg, and CuMg2 due to the presence of the liquid phase. In final products, the agglomerates of MgB2 grains had a size of 500–1000 nm, while the size of Cu2Mg and CuMg2 inclusions was within 0.5–2 μm. More... »

PAGES

18-25

References to SciGraph publications

  • 2014-11. Thermal explosion synthesis of a magnesium diboride powder in COMBUSTION, EXPLOSION, AND SHOCK WAVES
  • 2010-02. Al-Doping Effects on the Structural Change of MgB2 in JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.3103/s1061386218010065

    DOI

    http://dx.doi.org/10.3103/s1061386218010065

    DIMENSIONS

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