SHS hydrogenation of group IV metals as studied by time-resolved XRD View Full Text


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Article Info

DATE

2014-10

AUTHORS

D. Yu. Kovalev, A. E. Sytschev, I. D. Kovalev, A. I. Dekhtyar, I. V. Moiseeva

ABSTRACT

Reactions of SHS hydrogenation in Me-H systems (Me = Ti, Zr, Hf) were explored by time-resolved XRD. The SHS reaction yielding TiH2 was found to proceed in the following stages: α-Ti → α-Ti[H] → β-Ti[H] → δ-TiH2 (here β-Ti[H] stands for solid solution of hydrogen in β-Ti). SHS hydrogenation of Zr took place by the following scheme: α-Zr → β-Zr[H] → δ-ZrH1.5 → ɛ-ZrH2. The α-Hf → δ-HfHx transformation happened in one stage, without formation of intermediate β-Hf[H]. Our results shed new light on the kinetics and mechanism of SHS hydrogenation of metals. More... »

PAGES

198-202

References to SciGraph publications

  • 2013-04. SHS hydrogenation of titanium: Some structural and kinetic features in INTERNATIONAL JOURNAL OF SELF-PROPAGATING HIGH-TEMPERATURE SYNTHESIS
  • 2008-03. Interaction of transition metals and alloys with hydrogen in conventional SHS and radiation-assisted thermal explosion modes in INTERNATIONAL JOURNAL OF SELF-PROPAGATING HIGH-TEMPERATURE SYNTHESIS
  • 2010-12. Thermal decomposition of TiH2: A TRXRD study in INTERNATIONAL JOURNAL OF SELF-PROPAGATING HIGH-TEMPERATURE SYNTHESIS
  • 1992-09. A kinetic model for metal + nonmetal reactions in METALLURGICAL TRANSACTIONS A
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    http://scigraph.springernature.com/pub.10.3103/s1061386214040062

    DOI

    http://dx.doi.org/10.3103/s1061386214040062

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