Dehydrogenation of cyclohexane over SHS-produced Nickel-Zirconium alloy View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-09

AUTHORS

V. T. Minasyan, Kh. B. Manukyan, S. L. Kharatyan, R. A. Mnatsakanyan

ABSTRACT

Ni-Zr alloys were SHS-produced from Ni-Zi powder mixtures containing 4% Teflon powder as a chemical activator. In the presence of Teflon, the burning velocity increased by a factor of 15, at a combustion temperature of 1550°C. The synthesized powder was found to contain NiZr and Ni10Zr7 with a particle size of 1–5 μm and pores 100–300 μm in their size. In dehydrogenation of cyclohexane, the alloy exhibited a catalytic activity commencing from 160°C; at 500°C, the cyclohexane conversion attained a value of 78%. Our results illustrate the potential of SHS technology in production of heterogeneous catalysts active at relatively low temperatures. More... »

PAGES

150

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.3103/s1061386211030071

DOI

http://dx.doi.org/10.3103/s1061386211030071

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1044354420


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0904", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "National Academy of Sciences of Armenia", 
          "id": "https://www.grid.ac/institutes/grid.418094.0", 
          "name": [
            "Nalbandyan Institute of Chemical Physics, National Academy of Sciences, ul. Sevaka 5/2, 0014, Yerevan, Armenia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Minasyan", 
        "givenName": "V. T.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Yerevan State University", 
          "id": "https://www.grid.ac/institutes/grid.21072.36", 
          "name": [
            "Nalbandyan Institute of Chemical Physics, National Academy of Sciences, ul. Sevaka 5/2, 0014, Yerevan, Armenia", 
            "Yerevan State University, ul. Manukyana 1, 0025, Yerevan, Armenia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Manukyan", 
        "givenName": "Kh. B.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Yerevan State University", 
          "id": "https://www.grid.ac/institutes/grid.21072.36", 
          "name": [
            "Nalbandyan Institute of Chemical Physics, National Academy of Sciences, ul. Sevaka 5/2, 0014, Yerevan, Armenia", 
            "Yerevan State University, ul. Manukyana 1, 0025, Yerevan, Armenia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kharatyan", 
        "givenName": "S. L.", 
        "id": "sg:person.014521216433.38", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014521216433.38"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National Academy of Sciences of Armenia", 
          "id": "https://www.grid.ac/institutes/grid.418094.0", 
          "name": [
            "Nalbandyan Institute of Chemical Physics, National Academy of Sciences, ul. Sevaka 5/2, 0014, Yerevan, Armenia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mnatsakanyan", 
        "givenName": "R. A.", 
        "id": "sg:person.012737552417.81", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012737552417.81"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/0021-9517(72)90072-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011329630"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cej.2010.05.042", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012988518"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0925-8388(95)02143-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023940172"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.cattod.2004.10.012", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029875125"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/1.1424409", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039251827", 
          "https://doi.org/10.1134/1.1424409"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/9781847555229-00001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042115825"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0025-5408(00)00396-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045194727"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.4028/www.scientific.net/msf.343-346.901", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1072111329"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2011-09", 
    "datePublishedReg": "2011-09-01", 
    "description": "Ni-Zr alloys were SHS-produced from Ni-Zi powder mixtures containing 4% Teflon powder as a chemical activator. In the presence of Teflon, the burning velocity increased by a factor of 15, at a combustion temperature of 1550\u00b0C. The synthesized powder was found to contain NiZr and Ni10Zr7 with a particle size of 1\u20135 \u03bcm and pores 100\u2013300 \u03bcm in their size. In dehydrogenation of cyclohexane, the alloy exhibited a catalytic activity commencing from 160\u00b0C; at 500\u00b0C, the cyclohexane conversion attained a value of 78%. Our results illustrate the potential of SHS technology in production of heterogeneous catalysts active at relatively low temperatures.", 
    "genre": "non_research_article", 
    "id": "sg:pub.10.3103/s1061386211030071", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136584", 
        "issn": [
          "1061-3862", 
          "1934-788X"
        ], 
        "name": "International Journal of Self-Propagating High-Temperature Synthesis", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "20"
      }
    ], 
    "name": "Dehydrogenation of cyclohexane over SHS-produced Nickel-Zirconium alloy", 
    "pagination": "150", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "d3468d0de8345fe385a95d9ab3d8468cce8556c66845d3e3fef5e2beb8690e11"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.3103/s1061386211030071"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1044354420"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.3103/s1061386211030071", 
      "https://app.dimensions.ai/details/publication/pub.1044354420"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T22:30", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8690_00000507.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.3103/S1061386211030071"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.3103/s1061386211030071'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.3103/s1061386211030071'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.3103/s1061386211030071'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.3103/s1061386211030071'


 

This table displays all metadata directly associated to this object as RDF triples.

109 TRIPLES      21 PREDICATES      35 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.3103/s1061386211030071 schema:about anzsrc-for:09
2 anzsrc-for:0904
3 schema:author N13a9fe5a6df64279a78b2889efa3744d
4 schema:citation sg:pub.10.1134/1.1424409
5 https://doi.org/10.1016/0021-9517(72)90072-3
6 https://doi.org/10.1016/0925-8388(95)02143-4
7 https://doi.org/10.1016/j.cattod.2004.10.012
8 https://doi.org/10.1016/j.cej.2010.05.042
9 https://doi.org/10.1016/s0025-5408(00)00396-2
10 https://doi.org/10.1039/9781847555229-00001
11 https://doi.org/10.4028/www.scientific.net/msf.343-346.901
12 schema:datePublished 2011-09
13 schema:datePublishedReg 2011-09-01
14 schema:description Ni-Zr alloys were SHS-produced from Ni-Zi powder mixtures containing 4% Teflon powder as a chemical activator. In the presence of Teflon, the burning velocity increased by a factor of 15, at a combustion temperature of 1550°C. The synthesized powder was found to contain NiZr and Ni10Zr7 with a particle size of 1–5 μm and pores 100–300 μm in their size. In dehydrogenation of cyclohexane, the alloy exhibited a catalytic activity commencing from 160°C; at 500°C, the cyclohexane conversion attained a value of 78%. Our results illustrate the potential of SHS technology in production of heterogeneous catalysts active at relatively low temperatures.
15 schema:genre non_research_article
16 schema:inLanguage en
17 schema:isAccessibleForFree false
18 schema:isPartOf N574da69ad5964fe5a63e0fa63b22910b
19 N5ee18061df2c4aca9801db2dcb69a218
20 sg:journal.1136584
21 schema:name Dehydrogenation of cyclohexane over SHS-produced Nickel-Zirconium alloy
22 schema:pagination 150
23 schema:productId N226325783a20409f9bdf5a6b4cfe2830
24 N23f85d5922b0470ba05427ab5068d75d
25 N671803286ad1424dbe47a624dbf8dee5
26 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044354420
27 https://doi.org/10.3103/s1061386211030071
28 schema:sdDatePublished 2019-04-10T22:30
29 schema:sdLicense https://scigraph.springernature.com/explorer/license/
30 schema:sdPublisher Ncf7bb0423d684f2b83e66480b949f4e1
31 schema:url http://link.springer.com/10.3103/S1061386211030071
32 sgo:license sg:explorer/license/
33 sgo:sdDataset articles
34 rdf:type schema:ScholarlyArticle
35 N13a9fe5a6df64279a78b2889efa3744d rdf:first N1c573ad3e334483e848afa0985bf0783
36 rdf:rest N9f3459fe9a16451180d157e70cd908e7
37 N1a217db52bc645d0ae2f647b42342761 rdf:first sg:person.012737552417.81
38 rdf:rest rdf:nil
39 N1c573ad3e334483e848afa0985bf0783 schema:affiliation https://www.grid.ac/institutes/grid.418094.0
40 schema:familyName Minasyan
41 schema:givenName V. T.
42 rdf:type schema:Person
43 N226325783a20409f9bdf5a6b4cfe2830 schema:name dimensions_id
44 schema:value pub.1044354420
45 rdf:type schema:PropertyValue
46 N23f85d5922b0470ba05427ab5068d75d schema:name doi
47 schema:value 10.3103/s1061386211030071
48 rdf:type schema:PropertyValue
49 N52db6059c9e0477eb78408123571abe8 schema:affiliation https://www.grid.ac/institutes/grid.21072.36
50 schema:familyName Manukyan
51 schema:givenName Kh. B.
52 rdf:type schema:Person
53 N574da69ad5964fe5a63e0fa63b22910b schema:volumeNumber 20
54 rdf:type schema:PublicationVolume
55 N5ee18061df2c4aca9801db2dcb69a218 schema:issueNumber 3
56 rdf:type schema:PublicationIssue
57 N671803286ad1424dbe47a624dbf8dee5 schema:name readcube_id
58 schema:value d3468d0de8345fe385a95d9ab3d8468cce8556c66845d3e3fef5e2beb8690e11
59 rdf:type schema:PropertyValue
60 N9f3459fe9a16451180d157e70cd908e7 rdf:first N52db6059c9e0477eb78408123571abe8
61 rdf:rest Nc172dabd583542c1825d5212329a720a
62 Nc172dabd583542c1825d5212329a720a rdf:first sg:person.014521216433.38
63 rdf:rest N1a217db52bc645d0ae2f647b42342761
64 Ncf7bb0423d684f2b83e66480b949f4e1 schema:name Springer Nature - SN SciGraph project
65 rdf:type schema:Organization
66 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
67 schema:name Engineering
68 rdf:type schema:DefinedTerm
69 anzsrc-for:0904 schema:inDefinedTermSet anzsrc-for:
70 schema:name Chemical Engineering
71 rdf:type schema:DefinedTerm
72 sg:journal.1136584 schema:issn 1061-3862
73 1934-788X
74 schema:name International Journal of Self-Propagating High-Temperature Synthesis
75 rdf:type schema:Periodical
76 sg:person.012737552417.81 schema:affiliation https://www.grid.ac/institutes/grid.418094.0
77 schema:familyName Mnatsakanyan
78 schema:givenName R. A.
79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012737552417.81
80 rdf:type schema:Person
81 sg:person.014521216433.38 schema:affiliation https://www.grid.ac/institutes/grid.21072.36
82 schema:familyName Kharatyan
83 schema:givenName S. L.
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014521216433.38
85 rdf:type schema:Person
86 sg:pub.10.1134/1.1424409 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039251827
87 https://doi.org/10.1134/1.1424409
88 rdf:type schema:CreativeWork
89 https://doi.org/10.1016/0021-9517(72)90072-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011329630
90 rdf:type schema:CreativeWork
91 https://doi.org/10.1016/0925-8388(95)02143-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023940172
92 rdf:type schema:CreativeWork
93 https://doi.org/10.1016/j.cattod.2004.10.012 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029875125
94 rdf:type schema:CreativeWork
95 https://doi.org/10.1016/j.cej.2010.05.042 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012988518
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1016/s0025-5408(00)00396-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045194727
98 rdf:type schema:CreativeWork
99 https://doi.org/10.1039/9781847555229-00001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042115825
100 rdf:type schema:CreativeWork
101 https://doi.org/10.4028/www.scientific.net/msf.343-346.901 schema:sameAs https://app.dimensions.ai/details/publication/pub.1072111329
102 rdf:type schema:CreativeWork
103 https://www.grid.ac/institutes/grid.21072.36 schema:alternateName Yerevan State University
104 schema:name Nalbandyan Institute of Chemical Physics, National Academy of Sciences, ul. Sevaka 5/2, 0014, Yerevan, Armenia
105 Yerevan State University, ul. Manukyana 1, 0025, Yerevan, Armenia
106 rdf:type schema:Organization
107 https://www.grid.ac/institutes/grid.418094.0 schema:alternateName National Academy of Sciences of Armenia
108 schema:name Nalbandyan Institute of Chemical Physics, National Academy of Sciences, ul. Sevaka 5/2, 0014, Yerevan, Armenia
109 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...