Sulfobridged Polynuclear Complexes of Platinum(II) and Palladium(II) View Full Text


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Article Info

DATE

2018-11

AUTHORS

A. N. Azizova, D. B. Tagiyev, Sh. G. Gasimov, Kh. I. Gasanov

ABSTRACT

When the platinum(II) and palladium(II) salts interact with ligands such as cystamine-(mercamine) HSCH2CH2NH2 and 2-mercaptoethanol HSCH2CH2OH under certain conditions, polynuclear complexes of the compositions are obtained: [Pt6(SCH2CH2NH2)8]Cl4. 5H2O and [Pd6(SCH2CH2OH)8]Cl4. In a comparative study of the IR and X-ray spectra of synthesized complexes and ligands, as well as the results of X-ray diffraction studies, it was established that sulfur atoms of 2-mercaptoethanol occupy a bridge position with a mixed coordination of ligands in the palladium complex. In the platinum(II) complex bidentate coordination of ligands is realized through sulfur and nitrogen atoms. More... »

PAGES

293-297

Identifiers

URI

http://scigraph.springernature.com/pub.10.3103/s0027131418060032

DOI

http://dx.doi.org/10.3103/s0027131418060032

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1112087479


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