Solvent-free synthesis and properties of carboxymethyl starch fatty acid ester derivatives View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-02

AUTHORS

Viera Mazíková, Iva Sroková, Anna Ebringerová

ABSTRACT

Water-soluble, partially hydrophobized polysaccharides have become attractive due to their potential to act as polymeric surfactants. From carboxymethyl starch (CMS), water-soluble polymeric surfactants were prepared by esterification using two unconvential methods based on (A) a reaction with mixed anhydrides and (B) with methyl laureate (MELA) and methyl esters of the fatty acid complex of rape seed oil (MERO) under ‘solvent-free’ conditions. The obtained CMS derivatives were characterized by structural, surface-active and surfactant performance properties. Esterification using method B was successful in contrast to method A which yielded derivatives with a very low extent of esterification. Although the derivatives reduced the surface tension moderately, they exhibited remarkable emulsifying properties. The performance tests indicated good washing power and antiredeposition efficiency. The results suggest that suitable polymeric surfactants can be prepared by the unconventional esterification method B using both acylation agents. The preparations might substitute the expensive and invasive industrially applied conventional methods. More... »

PAGES

71-76

Identifiers

URI

http://scigraph.springernature.com/pub.10.2478/s11696-008-0088-x

DOI

http://dx.doi.org/10.2478/s11696-008-0088-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1035632075


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Macromolecular and Materials Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "name": [
            "Faculty of Industrial Technologies, Tren\u010d\u00edn University of Alexander Dub\u010dek, 020 01, P\u00fachov, Slovakia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Maz\u00edkov\u00e1", 
        "givenName": "Viera", 
        "id": "sg:person.0770657145.53", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0770657145.53"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "Faculty of Industrial Technologies, Tren\u010d\u00edn University of Alexander Dub\u010dek, 020 01, P\u00fachov, Slovakia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Srokov\u00e1", 
        "givenName": "Iva", 
        "id": "sg:person.0675222334.75", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0675222334.75"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.22539.3f", 
          "name": [
            "Institute of Chemistry, Center for Glycomics, Slovak Academy of Sciences, 845 38, Bratislava, Slovakia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ebringerov\u00e1", 
        "givenName": "Anna", 
        "id": "sg:person.016260736143.73", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016260736143.73"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1006/jcis.2002.8357", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000486329"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0144-8617(95)00143-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001863411"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(76)90267-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003953948"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(76)90267-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003953948"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.eurpolymj.2003.09.019", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004691662"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3950(68)90224-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005719020"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3950(68)90224-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005719020"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0927-7765(00)00151-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009542607"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/star.200600561", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014567696"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/star.200600507", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018205128"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0144-8617(01)00187-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018641362"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/mame.200300124", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027422845"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0960-8524(99)00034-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027584296"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11746-998-0047-2", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028821281", 
          "https://doi.org/10.1007/s11746-998-0047-2"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jcis.2004.08.178", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046687443"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/star.200400380", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049054591"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(84)90206-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052066939"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0032-3861(84)90206-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052066939"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0144-8617(00)00276-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053074172"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/cl.2004.1094", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1064489745"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.3139/113.100301", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1071026304"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2009-02", 
    "datePublishedReg": "2009-02-01", 
    "description": "Water-soluble, partially hydrophobized polysaccharides have become attractive due to their potential to act as polymeric surfactants. From carboxymethyl starch (CMS), water-soluble polymeric surfactants were prepared by esterification using two unconvential methods based on (A) a reaction with mixed anhydrides and (B) with methyl laureate (MELA) and methyl esters of the fatty acid complex of rape seed oil (MERO) under \u2018solvent-free\u2019 conditions. The obtained CMS derivatives were characterized by structural, surface-active and surfactant performance properties. Esterification using method B was successful in contrast to method A which yielded derivatives with a very low extent of esterification. Although the derivatives reduced the surface tension moderately, they exhibited remarkable emulsifying properties. The performance tests indicated good washing power and antiredeposition efficiency. The results suggest that suitable polymeric surfactants can be prepared by the unconventional esterification method B using both acylation agents. The preparations might substitute the expensive and invasive industrially applied conventional methods.", 
    "genre": "research_article", 
    "id": "sg:pub.10.2478/s11696-008-0088-x", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1006753", 
        "issn": [
          "2585-7290", 
          "0366-6352"
        ], 
        "name": "Chemical Papers", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "63"
      }
    ], 
    "name": "Solvent-free synthesis and properties of carboxymethyl starch fatty acid ester derivatives", 
    "pagination": "71-76", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "a9bd2ee4e7f14385501fdc21e96f663d4c83b7542797d6ad00c17f7d0c09bf6c"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.2478/s11696-008-0088-x"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1035632075"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.2478/s11696-008-0088-x", 
      "https://app.dimensions.ai/details/publication/pub.1035632075"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T23:23", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8693_00000506.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.2478/s11696-008-0088-x"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.2478/s11696-008-0088-x'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.2478/s11696-008-0088-x'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.2478/s11696-008-0088-x'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.2478/s11696-008-0088-x'


 

This table displays all metadata directly associated to this object as RDF triples.

134 TRIPLES      21 PREDICATES      45 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.2478/s11696-008-0088-x schema:about anzsrc-for:03
2 anzsrc-for:0303
3 schema:author Ne12e57c398c444ada7d94d14100cf01a
4 schema:citation sg:pub.10.1007/s11746-998-0047-2
5 https://doi.org/10.1002/mame.200300124
6 https://doi.org/10.1002/star.200400380
7 https://doi.org/10.1002/star.200600507
8 https://doi.org/10.1002/star.200600561
9 https://doi.org/10.1006/jcis.2002.8357
10 https://doi.org/10.1016/0032-3861(76)90267-6
11 https://doi.org/10.1016/0032-3861(84)90206-4
12 https://doi.org/10.1016/0032-3950(68)90224-4
13 https://doi.org/10.1016/0144-8617(95)00143-3
14 https://doi.org/10.1016/j.eurpolymj.2003.09.019
15 https://doi.org/10.1016/j.jcis.2004.08.178
16 https://doi.org/10.1016/s0144-8617(00)00276-9
17 https://doi.org/10.1016/s0144-8617(01)00187-4
18 https://doi.org/10.1016/s0927-7765(00)00151-x
19 https://doi.org/10.1016/s0960-8524(99)00034-6
20 https://doi.org/10.1246/cl.2004.1094
21 https://doi.org/10.3139/113.100301
22 schema:datePublished 2009-02
23 schema:datePublishedReg 2009-02-01
24 schema:description Water-soluble, partially hydrophobized polysaccharides have become attractive due to their potential to act as polymeric surfactants. From carboxymethyl starch (CMS), water-soluble polymeric surfactants were prepared by esterification using two unconvential methods based on (A) a reaction with mixed anhydrides and (B) with methyl laureate (MELA) and methyl esters of the fatty acid complex of rape seed oil (MERO) under ‘solvent-free’ conditions. The obtained CMS derivatives were characterized by structural, surface-active and surfactant performance properties. Esterification using method B was successful in contrast to method A which yielded derivatives with a very low extent of esterification. Although the derivatives reduced the surface tension moderately, they exhibited remarkable emulsifying properties. The performance tests indicated good washing power and antiredeposition efficiency. The results suggest that suitable polymeric surfactants can be prepared by the unconventional esterification method B using both acylation agents. The preparations might substitute the expensive and invasive industrially applied conventional methods.
25 schema:genre research_article
26 schema:inLanguage en
27 schema:isAccessibleForFree false
28 schema:isPartOf N1ef61d7ce76a45f389457aea1fd45fb3
29 N5f0df1e498344fec808c8e44e482ac8c
30 sg:journal.1006753
31 schema:name Solvent-free synthesis and properties of carboxymethyl starch fatty acid ester derivatives
32 schema:pagination 71-76
33 schema:productId N68c17c54d6da43e998614c95c23ff17a
34 N88e689fc3899420997148882157660c3
35 N8c2bc8be79974e3e8e1cbb09df899cae
36 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035632075
37 https://doi.org/10.2478/s11696-008-0088-x
38 schema:sdDatePublished 2019-04-10T23:23
39 schema:sdLicense https://scigraph.springernature.com/explorer/license/
40 schema:sdPublisher Nf5ec1fff86a943299a093f5eea07c188
41 schema:url http://link.springer.com/10.2478/s11696-008-0088-x
42 sgo:license sg:explorer/license/
43 sgo:sdDataset articles
44 rdf:type schema:ScholarlyArticle
45 N1ef61d7ce76a45f389457aea1fd45fb3 schema:volumeNumber 63
46 rdf:type schema:PublicationVolume
47 N5f0df1e498344fec808c8e44e482ac8c schema:issueNumber 1
48 rdf:type schema:PublicationIssue
49 N68c17c54d6da43e998614c95c23ff17a schema:name dimensions_id
50 schema:value pub.1035632075
51 rdf:type schema:PropertyValue
52 N8035528c44fd40c69f5e9c3a01984281 schema:name Faculty of Industrial Technologies, Trenčín University of Alexander Dubček, 020 01, Púchov, Slovakia
53 rdf:type schema:Organization
54 N88e689fc3899420997148882157660c3 schema:name readcube_id
55 schema:value a9bd2ee4e7f14385501fdc21e96f663d4c83b7542797d6ad00c17f7d0c09bf6c
56 rdf:type schema:PropertyValue
57 N8c2bc8be79974e3e8e1cbb09df899cae schema:name doi
58 schema:value 10.2478/s11696-008-0088-x
59 rdf:type schema:PropertyValue
60 N8cf42eb1e77a4857a835c00d7911ed03 rdf:first sg:person.016260736143.73
61 rdf:rest rdf:nil
62 Naee232d38c6644488f0164a4f1ee147e rdf:first sg:person.0675222334.75
63 rdf:rest N8cf42eb1e77a4857a835c00d7911ed03
64 Ne12e57c398c444ada7d94d14100cf01a rdf:first sg:person.0770657145.53
65 rdf:rest Naee232d38c6644488f0164a4f1ee147e
66 Nf5ec1fff86a943299a093f5eea07c188 schema:name Springer Nature - SN SciGraph project
67 rdf:type schema:Organization
68 Nfb16bcfd8df544e197419b79c3c597e4 schema:name Faculty of Industrial Technologies, Trenčín University of Alexander Dubček, 020 01, Púchov, Slovakia
69 rdf:type schema:Organization
70 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
71 schema:name Chemical Sciences
72 rdf:type schema:DefinedTerm
73 anzsrc-for:0303 schema:inDefinedTermSet anzsrc-for:
74 schema:name Macromolecular and Materials Chemistry
75 rdf:type schema:DefinedTerm
76 sg:journal.1006753 schema:issn 0366-6352
77 2585-7290
78 schema:name Chemical Papers
79 rdf:type schema:Periodical
80 sg:person.016260736143.73 schema:affiliation https://www.grid.ac/institutes/grid.22539.3f
81 schema:familyName Ebringerová
82 schema:givenName Anna
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016260736143.73
84 rdf:type schema:Person
85 sg:person.0675222334.75 schema:affiliation Nfb16bcfd8df544e197419b79c3c597e4
86 schema:familyName Sroková
87 schema:givenName Iva
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0675222334.75
89 rdf:type schema:Person
90 sg:person.0770657145.53 schema:affiliation N8035528c44fd40c69f5e9c3a01984281
91 schema:familyName Mazíková
92 schema:givenName Viera
93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0770657145.53
94 rdf:type schema:Person
95 sg:pub.10.1007/s11746-998-0047-2 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028821281
96 https://doi.org/10.1007/s11746-998-0047-2
97 rdf:type schema:CreativeWork
98 https://doi.org/10.1002/mame.200300124 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027422845
99 rdf:type schema:CreativeWork
100 https://doi.org/10.1002/star.200400380 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049054591
101 rdf:type schema:CreativeWork
102 https://doi.org/10.1002/star.200600507 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018205128
103 rdf:type schema:CreativeWork
104 https://doi.org/10.1002/star.200600561 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014567696
105 rdf:type schema:CreativeWork
106 https://doi.org/10.1006/jcis.2002.8357 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000486329
107 rdf:type schema:CreativeWork
108 https://doi.org/10.1016/0032-3861(76)90267-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003953948
109 rdf:type schema:CreativeWork
110 https://doi.org/10.1016/0032-3861(84)90206-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052066939
111 rdf:type schema:CreativeWork
112 https://doi.org/10.1016/0032-3950(68)90224-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005719020
113 rdf:type schema:CreativeWork
114 https://doi.org/10.1016/0144-8617(95)00143-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001863411
115 rdf:type schema:CreativeWork
116 https://doi.org/10.1016/j.eurpolymj.2003.09.019 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004691662
117 rdf:type schema:CreativeWork
118 https://doi.org/10.1016/j.jcis.2004.08.178 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046687443
119 rdf:type schema:CreativeWork
120 https://doi.org/10.1016/s0144-8617(00)00276-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053074172
121 rdf:type schema:CreativeWork
122 https://doi.org/10.1016/s0144-8617(01)00187-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018641362
123 rdf:type schema:CreativeWork
124 https://doi.org/10.1016/s0927-7765(00)00151-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1009542607
125 rdf:type schema:CreativeWork
126 https://doi.org/10.1016/s0960-8524(99)00034-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027584296
127 rdf:type schema:CreativeWork
128 https://doi.org/10.1246/cl.2004.1094 schema:sameAs https://app.dimensions.ai/details/publication/pub.1064489745
129 rdf:type schema:CreativeWork
130 https://doi.org/10.3139/113.100301 schema:sameAs https://app.dimensions.ai/details/publication/pub.1071026304
131 rdf:type schema:CreativeWork
132 https://www.grid.ac/institutes/grid.22539.3f schema:alternateName Institute of Chemistry
133 schema:name Institute of Chemistry, Center for Glycomics, Slovak Academy of Sciences, 845 38, Bratislava, Slovakia
134 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...