Glycosylated Metalloporphyrins as Neutral Carriers for PVC Membrane Electrodes View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2002-04-17

AUTHORS

Zhi-Zhang Li, Xiao-Bing Zhang, Can-Cheng Guo, Guo-Li Shen, Ru-Qin Yu

ABSTRACT

In this paper, the synthesis of a novel ionophore, chloro[5,10,15,20-tetrakis[2-(2,3,4,6-tetraacetyl-β-D-glucopyranosyl)-1-O-phenyl]porphinato]manganese (MnT(o-glu)PPCl), and its application as a neutral carrier for a PVC membrane electrode are described. The MnT(o-glu)PPCl-based PVC membrane electrode shows a potentiometric responses to SCN- over a concentration range of 3.4 × 10-7 - 1.0 × 10-1 mol L-1 with a Nernstian slope and a response time of 20 s. The electrode exhibits an anti-Hofmeister selectivity toward SCN- with respect to common coexisting anions. As active materials, MnT(o-glu)PPCl shows better selectivity toward SCN- than chloro(tetraphenylporphinato)manganese (MnTPPCl). The effect of the electrode membrane compositions has been studied and the experimental conditions were optimized. The electrode was applied to the determination of SCN- in body fluids with satisfactory results. More... »

PAGES

423-426

Identifiers

URI

http://scigraph.springernature.com/pub.10.2116/analsci.18.423

DOI

http://dx.doi.org/10.2116/analsci.18.423

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1030654105

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/11999516


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