Bismetalloporphyrin Complexes as Ionic Carriers for a Salicylate-Sensitive Electrode View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2000-12-17

AUTHORS

Xiao-Bing Zhang, Can-Cheng Guo, Li-Xin Jian, Guo-Li Shen, Ru-Qin Yu

ABSTRACT

Inspired by the success of using monometalloporphyrin complexes as ionic carriers for salicylate-sensitive electrodes, several µ-oxo-bismetalloporphyrin complexes were synthesized by the reaction of monometalloporphyrins with NaOH. A µ-oxo-bis[5-(p-hydroxylphenyl)-10,15,20-triphenyl-porphinatomanganese(III)] [[Mn(5-HP)TPP]2O]-based sensor responds to salicylate ion over the concentration range 6.3 × 10–7–1.0 × 10–1 mol L–1 with a Nernstian slope and a response time of 50 s, which is faster than that of monometalloporphyrin counterparts. The electrode exhibits anti¬Hofmeister selectivity toward salicylate with respect to common co-existing anions and shows a stable response for more than six months. The effect of the compositions of the electrode membrane has been studied and the experimental conditions optimized. The interaction mode of [Mn(5-HP)TPP]2O with Sal– has also been investigated. The electrode was preliminarily applied to the determination of salicylate in urine. More... »

PAGES

1285-1289

Identifiers

URI

http://scigraph.springernature.com/pub.10.2116/analsci.16.1285

DOI

http://dx.doi.org/10.2116/analsci.16.1285

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1000142328


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