High Temperature Superconductors in the La1+xBa2-x Cu3Oy System View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1987

AUTHORS

E. M. McCarron, C. C. Torardi, J. P. Attfield, K. J. Morrissey, A. W. Sleight, D. E. Cox, R. K. Bordia, W. E. Farneth, R. B. Flippen, M. A. Subramanian, E. Lopdrup, S. J. Poon

ABSTRACT

ABSTRACT In the perovskite-related La/Ba/Cu oxide system, the lanthanum ions can substitute on the barium sites due to a close match in the ionic radius of the two. Thus it is possible to make a solid solution La 1+x Ba 2- x Cu 3 O y where O ∼ x ≤ 0.5 and y ∼ 7. For the Ba-rich end member composition (x ∼ 0). the structure is orthorhombic. but as the La content increases and La begins to substitute on the Ba sites (disordered), the crystal symmetry changes from orthorhombic to tetragonal. In addition, the superconducting properties vary with increasing La content. In particular, the superconducting onset temperature is found to decrease linearly from 80 to 45 K over the compositional (x) range 0.0 → 0.375. In the La-rich limit (x = 0.5). 1/4 of the Ba atoms are replaced by La and superconductivity is lost. A correlation between oxygen ordering (annealing) and high T c is observed for orthorhombic LaBa 2 Cu 3 O y and inferred in the case of tetragonal La 1.25 Ba 1.75 Cu 3 O y . More... »

PAGES

101

Identifiers

URI

http://scigraph.springernature.com/pub.10.1557/proc-99-101

DOI

http://dx.doi.org/10.1557/proc-99-101

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1067961989


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