Nanocharacterization of Surface and Interface of Different Epoxy Networks View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2001

AUTHORS

X. Gu, D. Raghavan, D.L. Ho, L. Sung, M.R. VanLandingham, T. Nguyen

ABSTRACT

ABSTRACT The effect of network changes on the surface and interface properties of amine-cured epoxy has been investigated. Samples of different crosslinked epoxies are prepared by mixing stoichiometrically pure diglycidyl ether of bisphenol A (n=0.03) with different ratios of 1,3-bis(aminomethyl)cyclohexane (terafunctional amine) and cyclohexylmethylamine (difunctional amine). All samples are cured in CO 2 -free air. Both the film surface in contact with air and that in contact with the silicon substrate (the interface) are analyzed using atomic force microscopy (AFM) and nanoindentation. Small angle neutron scattering (SANS), attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy, and contact angle measurements, are used to assist in the interpretation of AFM results. Substantial morphological and mechanical differences are observed between the surface and the interface for different crosslinked epoxies. The findings have strong implications on the wettablity, adhesion, and durability of amine-cured epoxies. More... »

PAGES

dd10.9.1

Identifiers

URI

http://scigraph.springernature.com/pub.10.1557/proc-710-dd10.9.1

DOI

http://dx.doi.org/10.1557/proc-710-dd10.9.1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1067953658


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Chemistry Department, Howard University, Washington D.C. 20059", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Chemistry Department, Howard University, Washington D.C. 20059"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gu", 
        "givenName": "X.", 
        "id": "sg:person.014036357212.92", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014036357212.92"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Chemistry Department, Howard University, Washington D.C. 20059", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Chemistry Department, Howard University, Washington D.C. 20059"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Raghavan", 
        "givenName": "D.", 
        "id": "sg:person.01106512621.45", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01106512621.45"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "National Institute of Standards and Technology Center for Neutron Research, 100 Bureau Drive, stop 8562, Gaithersburg, MD 20899", 
          "id": "http://www.grid.ac/institutes/grid.94225.38", 
          "name": [
            "National Institute of Standards and Technology Center for Neutron Research, 100 Bureau Drive, stop 8562, Gaithersburg, MD 20899"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ho", 
        "givenName": "D.L.", 
        "id": "sg:person.010414442055.00", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010414442055.00"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Building and Fire Research Laboratory, National Institute of Standards and Technology, 100 Bureau Drive, stop 8621, Gaithersburg, MD 20899", 
          "id": "http://www.grid.ac/institutes/grid.94225.38", 
          "name": [
            "Building and Fire Research Laboratory, National Institute of Standards and Technology, 100 Bureau Drive, stop 8621, Gaithersburg, MD 20899"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sung", 
        "givenName": "L.", 
        "id": "sg:person.010421277673.86", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010421277673.86"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Building and Fire Research Laboratory, National Institute of Standards and Technology, 100 Bureau Drive, stop 8621, Gaithersburg, MD 20899", 
          "id": "http://www.grid.ac/institutes/grid.94225.38", 
          "name": [
            "Building and Fire Research Laboratory, National Institute of Standards and Technology, 100 Bureau Drive, stop 8621, Gaithersburg, MD 20899"
          ], 
          "type": "Organization"
        }, 
        "familyName": "VanLandingham", 
        "givenName": "M.R.", 
        "id": "sg:person.012726665630.31", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012726665630.31"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Building and Fire Research Laboratory, National Institute of Standards and Technology, 100 Bureau Drive, stop 8621, Gaithersburg, MD 20899", 
          "id": "http://www.grid.ac/institutes/grid.94225.38", 
          "name": [
            "Building and Fire Research Laboratory, National Institute of Standards and Technology, 100 Bureau Drive, stop 8621, Gaithersburg, MD 20899"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Nguyen", 
        "givenName": "T.", 
        "id": "sg:person.010651314036.14", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010651314036.14"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2001", 
    "datePublishedReg": "2001-01-01", 
    "description": "ABSTRACT  The effect of network changes on the surface and interface properties of amine-cured epoxy has been investigated. Samples of different crosslinked epoxies are prepared by mixing stoichiometrically pure diglycidyl ether of bisphenol A (n=0.03) with different ratios of 1,3-bis(aminomethyl)cyclohexane (terafunctional amine) and cyclohexylmethylamine (difunctional amine). All samples are cured in CO 2 -free air. Both the film surface in contact with air and that in contact with the silicon substrate (the interface) are analyzed using atomic force microscopy (AFM) and nanoindentation. Small angle neutron scattering (SANS), attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy, and contact angle measurements, are used to assist in the interpretation of AFM results. Substantial morphological and mechanical differences are observed between the surface and the interface for different crosslinked epoxies. The findings have strong implications on the wettablity, adhesion, and durability of amine-cured epoxies. ", 
    "genre": "article", 
    "id": "sg:pub.10.1557/proc-710-dd10.9.1", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1297379", 
        "issn": [
          "0272-9172", 
          "2059-8521"
        ], 
        "name": "MRS Advances", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "710"
      }
    ], 
    "keywords": [
      "small angle neutron scattering", 
      "atomic force microscopy", 
      "amine-cured epoxy", 
      "total reflection Fourier transform", 
      "reflection Fourier transform", 
      "contact angle measurements", 
      "angle neutron scattering", 
      "angle measurements", 
      "force microscopy", 
      "Fourier transform", 
      "AFM results", 
      "neutron scattering", 
      "film surface", 
      "diglycidyl ether", 
      "bisphenol A", 
      "epoxy networks", 
      "different ratios", 
      "silicon substrate", 
      "surface", 
      "wettablity", 
      "spectroscopy", 
      "epoxy", 
      "ether", 
      "air", 
      "nanocharacterization", 
      "transform", 
      "microscopy", 
      "durability", 
      "interface", 
      "samples", 
      "properties", 
      "substrate", 
      "scattering", 
      "contact", 
      "nanoindentation", 
      "adhesion", 
      "measurements", 
      "ratio", 
      "strong implications", 
      "effect", 
      "results", 
      "changes", 
      "Abstract", 
      "interpretation", 
      "network", 
      "mechanical differences", 
      "differences", 
      "implications", 
      "findings", 
      "network changes", 
      "pure diglycidyl ether", 
      "cyclohexylmethylamine", 
      "CO 2 -free air", 
      "Nanocharacterization of Surface", 
      "Different Epoxy Networks"
    ], 
    "name": "Nanocharacterization of Surface and Interface of Different Epoxy Networks", 
    "pagination": "dd10.9.1", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1067953658"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1557/proc-710-dd10.9.1"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1557/proc-710-dd10.9.1", 
      "https://app.dimensions.ai/details/publication/pub.1067953658"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-01-01T18:10", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/article/article_330.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1557/proc-710-dd10.9.1"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1557/proc-710-dd10.9.1'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1557/proc-710-dd10.9.1'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1557/proc-710-dd10.9.1'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1557/proc-710-dd10.9.1'


 

This table displays all metadata directly associated to this object as RDF triples.

150 TRIPLES      21 PREDICATES      80 URIs      72 LITERALS      5 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1557/proc-710-dd10.9.1 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Naa7093678cf1403ea28a2470984ca32e
4 schema:datePublished 2001
5 schema:datePublishedReg 2001-01-01
6 schema:description ABSTRACT The effect of network changes on the surface and interface properties of amine-cured epoxy has been investigated. Samples of different crosslinked epoxies are prepared by mixing stoichiometrically pure diglycidyl ether of bisphenol A (n=0.03) with different ratios of 1,3-bis(aminomethyl)cyclohexane (terafunctional amine) and cyclohexylmethylamine (difunctional amine). All samples are cured in CO 2 -free air. Both the film surface in contact with air and that in contact with the silicon substrate (the interface) are analyzed using atomic force microscopy (AFM) and nanoindentation. Small angle neutron scattering (SANS), attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy, and contact angle measurements, are used to assist in the interpretation of AFM results. Substantial morphological and mechanical differences are observed between the surface and the interface for different crosslinked epoxies. The findings have strong implications on the wettablity, adhesion, and durability of amine-cured epoxies.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf Nc0c99327a3c8449da08c85e2a3971453
11 sg:journal.1297379
12 schema:keywords AFM results
13 Abstract
14 CO 2 -free air
15 Different Epoxy Networks
16 Fourier transform
17 Nanocharacterization of Surface
18 adhesion
19 air
20 amine-cured epoxy
21 angle measurements
22 angle neutron scattering
23 atomic force microscopy
24 bisphenol A
25 changes
26 contact
27 contact angle measurements
28 cyclohexylmethylamine
29 differences
30 different ratios
31 diglycidyl ether
32 durability
33 effect
34 epoxy
35 epoxy networks
36 ether
37 film surface
38 findings
39 force microscopy
40 implications
41 interface
42 interpretation
43 measurements
44 mechanical differences
45 microscopy
46 nanocharacterization
47 nanoindentation
48 network
49 network changes
50 neutron scattering
51 properties
52 pure diglycidyl ether
53 ratio
54 reflection Fourier transform
55 results
56 samples
57 scattering
58 silicon substrate
59 small angle neutron scattering
60 spectroscopy
61 strong implications
62 substrate
63 surface
64 total reflection Fourier transform
65 transform
66 wettablity
67 schema:name Nanocharacterization of Surface and Interface of Different Epoxy Networks
68 schema:pagination dd10.9.1
69 schema:productId N2ae436b8cdba4d9293c1d23bb8a0b52a
70 N4577c8579c144556b5b1a7960f3bf1d9
71 schema:sameAs https://app.dimensions.ai/details/publication/pub.1067953658
72 https://doi.org/10.1557/proc-710-dd10.9.1
73 schema:sdDatePublished 2022-01-01T18:10
74 schema:sdLicense https://scigraph.springernature.com/explorer/license/
75 schema:sdPublisher N7dbc71bad2b44d1d8f57f8191a4cd02d
76 schema:url https://doi.org/10.1557/proc-710-dd10.9.1
77 sgo:license sg:explorer/license/
78 sgo:sdDataset articles
79 rdf:type schema:ScholarlyArticle
80 N26181b05f4f04c4aa36b8caa08e48a97 rdf:first sg:person.012726665630.31
81 rdf:rest N541c5e411fa54b4994b4223ada8b3dbe
82 N2ae436b8cdba4d9293c1d23bb8a0b52a schema:name doi
83 schema:value 10.1557/proc-710-dd10.9.1
84 rdf:type schema:PropertyValue
85 N4577c8579c144556b5b1a7960f3bf1d9 schema:name dimensions_id
86 schema:value pub.1067953658
87 rdf:type schema:PropertyValue
88 N541c5e411fa54b4994b4223ada8b3dbe rdf:first sg:person.010651314036.14
89 rdf:rest rdf:nil
90 N7dbc71bad2b44d1d8f57f8191a4cd02d schema:name Springer Nature - SN SciGraph project
91 rdf:type schema:Organization
92 N80cdb10f822540969228ae697b6ba0e0 rdf:first sg:person.010414442055.00
93 rdf:rest Nd46fbadded4c4cb8935b05bd9f6140f1
94 Naa7093678cf1403ea28a2470984ca32e rdf:first sg:person.014036357212.92
95 rdf:rest Nf20d28baa2b74d08b07378fb76701a1f
96 Nc0c99327a3c8449da08c85e2a3971453 schema:volumeNumber 710
97 rdf:type schema:PublicationVolume
98 Nd46fbadded4c4cb8935b05bd9f6140f1 rdf:first sg:person.010421277673.86
99 rdf:rest N26181b05f4f04c4aa36b8caa08e48a97
100 Nf20d28baa2b74d08b07378fb76701a1f rdf:first sg:person.01106512621.45
101 rdf:rest N80cdb10f822540969228ae697b6ba0e0
102 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
103 schema:name Chemical Sciences
104 rdf:type schema:DefinedTerm
105 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
106 schema:name Physical Chemistry (incl. Structural)
107 rdf:type schema:DefinedTerm
108 sg:journal.1297379 schema:issn 0272-9172
109 2059-8521
110 schema:name MRS Advances
111 schema:publisher Springer Nature
112 rdf:type schema:Periodical
113 sg:person.010414442055.00 schema:affiliation grid-institutes:grid.94225.38
114 schema:familyName Ho
115 schema:givenName D.L.
116 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010414442055.00
117 rdf:type schema:Person
118 sg:person.010421277673.86 schema:affiliation grid-institutes:grid.94225.38
119 schema:familyName Sung
120 schema:givenName L.
121 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010421277673.86
122 rdf:type schema:Person
123 sg:person.010651314036.14 schema:affiliation grid-institutes:grid.94225.38
124 schema:familyName Nguyen
125 schema:givenName T.
126 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010651314036.14
127 rdf:type schema:Person
128 sg:person.01106512621.45 schema:affiliation grid-institutes:None
129 schema:familyName Raghavan
130 schema:givenName D.
131 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01106512621.45
132 rdf:type schema:Person
133 sg:person.012726665630.31 schema:affiliation grid-institutes:grid.94225.38
134 schema:familyName VanLandingham
135 schema:givenName M.R.
136 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012726665630.31
137 rdf:type schema:Person
138 sg:person.014036357212.92 schema:affiliation grid-institutes:None
139 schema:familyName Gu
140 schema:givenName X.
141 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014036357212.92
142 rdf:type schema:Person
143 grid-institutes:None schema:alternateName Chemistry Department, Howard University, Washington D.C. 20059
144 schema:name Chemistry Department, Howard University, Washington D.C. 20059
145 rdf:type schema:Organization
146 grid-institutes:grid.94225.38 schema:alternateName Building and Fire Research Laboratory, National Institute of Standards and Technology, 100 Bureau Drive, stop 8621, Gaithersburg, MD 20899
147 National Institute of Standards and Technology Center for Neutron Research, 100 Bureau Drive, stop 8562, Gaithersburg, MD 20899
148 schema:name Building and Fire Research Laboratory, National Institute of Standards and Technology, 100 Bureau Drive, stop 8621, Gaithersburg, MD 20899
149 National Institute of Standards and Technology Center for Neutron Research, 100 Bureau Drive, stop 8562, Gaithersburg, MD 20899
150 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...