Hydrogen Storage Properties, Metallographic Structures and Phase Transitions of Mg-based Alloys Prepared by Super Lamination Technique View Full Text


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Article Info

DATE

2008

AUTHORS

Nobuhiko Takeichi, Koji Tanaka, Hideaki Tanaka, Nobuhiro Kuriyama, Tamotsu T Ueda, Makoto Tsukahara, Hiroshi Miyamura, Shiomi Kikuchi

ABSTRACT

We have prepared Mg/Pd laminate composites with (Mg/Pd)=6, 3 and 2.5 atom ratios, by a super lamination technique. The homogeneous Mg-Pd intermetallic compounds, Mg 6 Pd, Mg 3 Pd and Mg 5 Pd 2 , are formed during the initial activation process. We investigated the hydrogen storage properties of these materials. The compounds can reversibly absorb and desorb a large amount of hydrogen, up to 1.46˜0.9 H/M, at 573 K. Except for the Mg 5 Pd 2 -hydrogen system, the pressure composition-isotherms show two plateaux. The mechanism of the phase transition during hydrogenation/dehydrogenation was analyzed by in-situ XRD measurements. These intermetallic compounds absorb and desorb hydrogen through reversible multistage disproportionation and recombination processes. More... »

PAGES

1128-u01-04

Identifiers

URI

http://scigraph.springernature.com/pub.10.1557/proc-1128-u01-04

DOI

http://dx.doi.org/10.1557/proc-1128-u01-04

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1067907512


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