Mechanochemical-hydrothermal preparation of crystalline hydroxyapatite powders at room temperature View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2001-05

AUTHORS

Pavel Shuk, Wojciech L. Suchanek, Tian Hao, Eric Gulliver, Richard E. Riman, Mamoru Senna, Kevor S. TenHuisen, Victor F. Janas

ABSTRACT

Crystalline hydroxyapatite (HAp) powders were prepared at room temperature from heterogeneous reaction between Ca(OH) 2 powders and (NH 4 ) 2 HPO 4 solutions via the mechanochemical-hydrothermal route. X-ray diffraction, infrared spectroscopy, thermogravimetric characterization, and chemical analysis were performed, and it was determined that the room temperature products were phase-pure, thermally stable HAp with a nearly stoichiometric composition. Dynamic light scattering revealed that the dispersed particle size distribution of the room temperature HAp powders was in the range of 0.15–3.0 μm with a specific surface area of ≈90 m 2 /g. Both specific surface area measurements and scanning electron microscopy confirmed that the HAp powders consisted of agglomerates containing hundreds of ≈20 nm HAp crystals. More... »

PAGES

1231-1234

Identifiers

URI

http://scigraph.springernature.com/pub.10.1557/jmr.2001.0170

DOI

http://dx.doi.org/10.1557/jmr.2001.0170

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1046237570


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/02", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0299", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Other Physical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Department of Ceramic and Materials Engineering, Rutgers University, 607 Taylor Road, Piscataway, New Jersey 08854-8087", 
          "id": "http://www.grid.ac/institutes/grid.430387.b", 
          "name": [
            "Department of Ceramic and Materials Engineering, Rutgers University, 607 Taylor Road, Piscataway, New Jersey 08854-8087"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shuk", 
        "givenName": "Pavel", 
        "id": "sg:person.014612156073.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014612156073.01"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Ceramic and Materials Engineering, Rutgers University, 607 Taylor Road, Piscataway, New Jersey 08854-8087", 
          "id": "http://www.grid.ac/institutes/grid.430387.b", 
          "name": [
            "Department of Ceramic and Materials Engineering, Rutgers University, 607 Taylor Road, Piscataway, New Jersey 08854-8087"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Suchanek", 
        "givenName": "Wojciech L.", 
        "id": "sg:person.012164674334.04", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012164674334.04"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Ceramic and Materials Engineering, Rutgers University, 607 Taylor Road, Piscataway, New Jersey 08854-8087", 
          "id": "http://www.grid.ac/institutes/grid.430387.b", 
          "name": [
            "Department of Ceramic and Materials Engineering, Rutgers University, 607 Taylor Road, Piscataway, New Jersey 08854-8087"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Hao", 
        "givenName": "Tian", 
        "id": "sg:person.01036762003.58", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01036762003.58"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Ceramic and Materials Engineering, Rutgers University, 607 Taylor Road, Piscataway, New Jersey 08854-8087", 
          "id": "http://www.grid.ac/institutes/grid.430387.b", 
          "name": [
            "Department of Ceramic and Materials Engineering, Rutgers University, 607 Taylor Road, Piscataway, New Jersey 08854-8087"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gulliver", 
        "givenName": "Eric", 
        "id": "sg:person.07462013547.15", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07462013547.15"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Ceramic and Materials Engineering, Rutgers University, 607 Taylor Road, Piscataway, New Jersey 08854-8087", 
          "id": "http://www.grid.ac/institutes/grid.430387.b", 
          "name": [
            "Department of Ceramic and Materials Engineering, Rutgers University, 607 Taylor Road, Piscataway, New Jersey 08854-8087"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Riman", 
        "givenName": "Richard E.", 
        "id": "sg:person.01175603410.96", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01175603410.96"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Yokohama 223-8522, Japan", 
          "id": "http://www.grid.ac/institutes/grid.26091.3c", 
          "name": [
            "Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Yokohama 223-8522, Japan"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Senna", 
        "givenName": "Mamoru", 
        "id": "sg:person.011363404413.06", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011363404413.06"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Johnson & Johnson Corporate Biomaterials Center, Rt. 22 W, P.O. Box 151, Somerville, New Jersey 08876-0151", 
          "id": "http://www.grid.ac/institutes/grid.417429.d", 
          "name": [
            "Johnson & Johnson Corporate Biomaterials Center, Rt. 22 W, P.O. Box 151, Somerville, New Jersey 08876-0151"
          ], 
          "type": "Organization"
        }, 
        "familyName": "TenHuisen", 
        "givenName": "Kevor S.", 
        "id": "sg:person.01351607574.53", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01351607574.53"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Johnson & Johnson Corporate Biomaterials Center, Rt. 22 W, P.O. Box 151, Somerville, New Jersey 08876-0151", 
          "id": "http://www.grid.ac/institutes/grid.417429.d", 
          "name": [
            "Johnson & Johnson Corporate Biomaterials Center, Rt. 22 W, P.O. Box 151, Somerville, New Jersey 08876-0151"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Janas", 
        "givenName": "Victor F.", 
        "id": "sg:person.015746266307.11", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015746266307.11"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1557/jmr.1995.0521", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007772987", 
          "https://doi.org/10.1557/jmr.1995.0521"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1557/jmr.1998.0015", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039886539", 
          "https://doi.org/10.1557/jmr.1998.0015"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf01209240", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012025751", 
          "https://doi.org/10.1007/bf01209240"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00372184", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050502298", 
          "https://doi.org/10.1007/bf00372184"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2001-05", 
    "datePublishedReg": "2001-05-01", 
    "description": " Crystalline hydroxyapatite (HAp) powders were prepared at room temperature from heterogeneous reaction between Ca(OH) 2 powders and (NH 4 ) 2 HPO 4 solutions via the mechanochemical-hydrothermal route. X-ray diffraction, infrared spectroscopy, thermogravimetric characterization, and chemical analysis were performed, and it was determined that the room temperature products were phase-pure, thermally stable HAp with a nearly stoichiometric composition. Dynamic light scattering revealed that the dispersed particle size distribution of the room temperature HAp powders was in the range of 0.15\u20133.0 \u03bcm with a specific surface area of \u224890 m 2 /g. Both specific surface area measurements and scanning electron microscopy confirmed that the HAp powders consisted of agglomerates containing hundreds of \u224820 nm HAp crystals. ", 
    "genre": "article", 
    "id": "sg:pub.10.1557/jmr.2001.0170", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1357547", 
        "issn": [
          "0884-2914", 
          "2044-5326"
        ], 
        "name": "Journal of Materials Research", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "5", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "16"
      }
    ], 
    "keywords": [
      "crystalline hydroxyapatite powder", 
      "specific surface area measurements", 
      "dynamic light scattering", 
      "surface area measurements", 
      "room-temperature products", 
      "HPO 4 solution", 
      "specific surface area", 
      "X-ray diffraction", 
      "mechanochemical-hydrothermal route", 
      "HAp powders", 
      "stable HAp", 
      "room temperature", 
      "hydroxyapatite powder", 
      "heterogeneous reactions", 
      "thermogravimetric characterization", 
      "light scattering", 
      "chemical analysis", 
      "surface area", 
      "area measurements", 
      "HAp crystals", 
      "electron microscopy", 
      "particle size distribution", 
      "stoichiometric composition", 
      "size distribution", 
      "powder", 
      "spectroscopy", 
      "diffraction", 
      "reaction", 
      "preparation", 
      "temperature", 
      "microscopy", 
      "agglomerates", 
      "HAp", 
      "crystals", 
      "route", 
      "characterization", 
      "products", 
      "solution", 
      "composition", 
      "scattering", 
      "range", 
      "measurements", 
      "hundreds", 
      "temperature products", 
      "area", 
      "analysis", 
      "distribution"
    ], 
    "name": "Mechanochemical-hydrothermal preparation of crystalline hydroxyapatite powders at room temperature", 
    "pagination": "1231-1234", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1046237570"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1557/jmr.2001.0170"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1557/jmr.2001.0170", 
      "https://app.dimensions.ai/details/publication/pub.1046237570"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-08-04T16:53", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220804/entities/gbq_results/article/article_329.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1557/jmr.2001.0170"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1557/jmr.2001.0170'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1557/jmr.2001.0170'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1557/jmr.2001.0170'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1557/jmr.2001.0170'


 

This table displays all metadata directly associated to this object as RDF triples.

175 TRIPLES      21 PREDICATES      76 URIs      64 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1557/jmr.2001.0170 schema:about anzsrc-for:02
2 anzsrc-for:0299
3 schema:author Ndcdd541ca45c49a8a97755ab1a049e41
4 schema:citation sg:pub.10.1007/bf00372184
5 sg:pub.10.1007/bf01209240
6 sg:pub.10.1557/jmr.1995.0521
7 sg:pub.10.1557/jmr.1998.0015
8 schema:datePublished 2001-05
9 schema:datePublishedReg 2001-05-01
10 schema:description Crystalline hydroxyapatite (HAp) powders were prepared at room temperature from heterogeneous reaction between Ca(OH) 2 powders and (NH 4 ) 2 HPO 4 solutions via the mechanochemical-hydrothermal route. X-ray diffraction, infrared spectroscopy, thermogravimetric characterization, and chemical analysis were performed, and it was determined that the room temperature products were phase-pure, thermally stable HAp with a nearly stoichiometric composition. Dynamic light scattering revealed that the dispersed particle size distribution of the room temperature HAp powders was in the range of 0.15–3.0 μm with a specific surface area of ≈90 m 2 /g. Both specific surface area measurements and scanning electron microscopy confirmed that the HAp powders consisted of agglomerates containing hundreds of ≈20 nm HAp crystals.
11 schema:genre article
12 schema:isAccessibleForFree false
13 schema:isPartOf N1bbd55cddf9f45099e6897d4c2b03f8b
14 Ne973511973d54ac7ab446b2a05cbdf31
15 sg:journal.1357547
16 schema:keywords HAp
17 HAp crystals
18 HAp powders
19 HPO 4 solution
20 X-ray diffraction
21 agglomerates
22 analysis
23 area
24 area measurements
25 characterization
26 chemical analysis
27 composition
28 crystalline hydroxyapatite powder
29 crystals
30 diffraction
31 distribution
32 dynamic light scattering
33 electron microscopy
34 heterogeneous reactions
35 hundreds
36 hydroxyapatite powder
37 light scattering
38 measurements
39 mechanochemical-hydrothermal route
40 microscopy
41 particle size distribution
42 powder
43 preparation
44 products
45 range
46 reaction
47 room temperature
48 room-temperature products
49 route
50 scattering
51 size distribution
52 solution
53 specific surface area
54 specific surface area measurements
55 spectroscopy
56 stable HAp
57 stoichiometric composition
58 surface area
59 surface area measurements
60 temperature
61 temperature products
62 thermogravimetric characterization
63 schema:name Mechanochemical-hydrothermal preparation of crystalline hydroxyapatite powders at room temperature
64 schema:pagination 1231-1234
65 schema:productId N4052dceaa201417497df88791017aeb5
66 Nff699b11d2cc4c998e0f03bdc7ae0903
67 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046237570
68 https://doi.org/10.1557/jmr.2001.0170
69 schema:sdDatePublished 2022-08-04T16:53
70 schema:sdLicense https://scigraph.springernature.com/explorer/license/
71 schema:sdPublisher N79878ccbf8be41a998a9da24733fde47
72 schema:url https://doi.org/10.1557/jmr.2001.0170
73 sgo:license sg:explorer/license/
74 sgo:sdDataset articles
75 rdf:type schema:ScholarlyArticle
76 N110405556bcc4cd9be969a58613663e8 rdf:first sg:person.012164674334.04
77 rdf:rest Nd8c35ddd4ad146798d14ed4aea29b699
78 N1bbd55cddf9f45099e6897d4c2b03f8b schema:issueNumber 5
79 rdf:type schema:PublicationIssue
80 N2259edc6eb984004a7b5cd40eb3b44de rdf:first sg:person.07462013547.15
81 rdf:rest Nbc4dc08e2ad6474188d9c54bfa8394b6
82 N4052dceaa201417497df88791017aeb5 schema:name doi
83 schema:value 10.1557/jmr.2001.0170
84 rdf:type schema:PropertyValue
85 N476abe7bb8ae4012bf9339460c668fa0 rdf:first sg:person.01351607574.53
86 rdf:rest N86c27bf2b1ed43b2997968b92706772c
87 N79878ccbf8be41a998a9da24733fde47 schema:name Springer Nature - SN SciGraph project
88 rdf:type schema:Organization
89 N86c27bf2b1ed43b2997968b92706772c rdf:first sg:person.015746266307.11
90 rdf:rest rdf:nil
91 Nbc4dc08e2ad6474188d9c54bfa8394b6 rdf:first sg:person.01175603410.96
92 rdf:rest Ndaa145e4f1bc4997b21c412243f3a391
93 Nd8c35ddd4ad146798d14ed4aea29b699 rdf:first sg:person.01036762003.58
94 rdf:rest N2259edc6eb984004a7b5cd40eb3b44de
95 Ndaa145e4f1bc4997b21c412243f3a391 rdf:first sg:person.011363404413.06
96 rdf:rest N476abe7bb8ae4012bf9339460c668fa0
97 Ndcdd541ca45c49a8a97755ab1a049e41 rdf:first sg:person.014612156073.01
98 rdf:rest N110405556bcc4cd9be969a58613663e8
99 Ne973511973d54ac7ab446b2a05cbdf31 schema:volumeNumber 16
100 rdf:type schema:PublicationVolume
101 Nff699b11d2cc4c998e0f03bdc7ae0903 schema:name dimensions_id
102 schema:value pub.1046237570
103 rdf:type schema:PropertyValue
104 anzsrc-for:02 schema:inDefinedTermSet anzsrc-for:
105 schema:name Physical Sciences
106 rdf:type schema:DefinedTerm
107 anzsrc-for:0299 schema:inDefinedTermSet anzsrc-for:
108 schema:name Other Physical Sciences
109 rdf:type schema:DefinedTerm
110 sg:journal.1357547 schema:issn 0884-2914
111 2044-5326
112 schema:name Journal of Materials Research
113 schema:publisher Springer Nature
114 rdf:type schema:Periodical
115 sg:person.01036762003.58 schema:affiliation grid-institutes:grid.430387.b
116 schema:familyName Hao
117 schema:givenName Tian
118 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01036762003.58
119 rdf:type schema:Person
120 sg:person.011363404413.06 schema:affiliation grid-institutes:grid.26091.3c
121 schema:familyName Senna
122 schema:givenName Mamoru
123 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011363404413.06
124 rdf:type schema:Person
125 sg:person.01175603410.96 schema:affiliation grid-institutes:grid.430387.b
126 schema:familyName Riman
127 schema:givenName Richard E.
128 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01175603410.96
129 rdf:type schema:Person
130 sg:person.012164674334.04 schema:affiliation grid-institutes:grid.430387.b
131 schema:familyName Suchanek
132 schema:givenName Wojciech L.
133 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012164674334.04
134 rdf:type schema:Person
135 sg:person.01351607574.53 schema:affiliation grid-institutes:grid.417429.d
136 schema:familyName TenHuisen
137 schema:givenName Kevor S.
138 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01351607574.53
139 rdf:type schema:Person
140 sg:person.014612156073.01 schema:affiliation grid-institutes:grid.430387.b
141 schema:familyName Shuk
142 schema:givenName Pavel
143 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014612156073.01
144 rdf:type schema:Person
145 sg:person.015746266307.11 schema:affiliation grid-institutes:grid.417429.d
146 schema:familyName Janas
147 schema:givenName Victor F.
148 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015746266307.11
149 rdf:type schema:Person
150 sg:person.07462013547.15 schema:affiliation grid-institutes:grid.430387.b
151 schema:familyName Gulliver
152 schema:givenName Eric
153 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07462013547.15
154 rdf:type schema:Person
155 sg:pub.10.1007/bf00372184 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050502298
156 https://doi.org/10.1007/bf00372184
157 rdf:type schema:CreativeWork
158 sg:pub.10.1007/bf01209240 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012025751
159 https://doi.org/10.1007/bf01209240
160 rdf:type schema:CreativeWork
161 sg:pub.10.1557/jmr.1995.0521 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007772987
162 https://doi.org/10.1557/jmr.1995.0521
163 rdf:type schema:CreativeWork
164 sg:pub.10.1557/jmr.1998.0015 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039886539
165 https://doi.org/10.1557/jmr.1998.0015
166 rdf:type schema:CreativeWork
167 grid-institutes:grid.26091.3c schema:alternateName Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Yokohama 223-8522, Japan
168 schema:name Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Yokohama 223-8522, Japan
169 rdf:type schema:Organization
170 grid-institutes:grid.417429.d schema:alternateName Johnson & Johnson Corporate Biomaterials Center, Rt. 22 W, P.O. Box 151, Somerville, New Jersey 08876-0151
171 schema:name Johnson & Johnson Corporate Biomaterials Center, Rt. 22 W, P.O. Box 151, Somerville, New Jersey 08876-0151
172 rdf:type schema:Organization
173 grid-institutes:grid.430387.b schema:alternateName Department of Ceramic and Materials Engineering, Rutgers University, 607 Taylor Road, Piscataway, New Jersey 08854-8087
174 schema:name Department of Ceramic and Materials Engineering, Rutgers University, 607 Taylor Road, Piscataway, New Jersey 08854-8087
175 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...