Mechanistic studies in combustion synthesis of Ni3Al and Ni3Al-matrix composites View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

1994-05

AUTHORS

Jean-Pascal Lebrat, Arvind Varma, Paul J. McGinn

ABSTRACT

Nickel aluminides exhibit limited ductility and toughness at room temperature. One way to improve these characteristics is by adding ceramic reinforcements to the matrix. In this paper, we have studied the combustion synthesis of Ni 3 Al and Ni 3 Al-matrix composites, using the self-propagating high-temperature synthesis (SHS) mode. First, studies of the Ni 3 Al synthesis were carried out by quenching the reaction during its progress, which revealed the mechanism of the synthesis. The influence of Al 2 O 3 and SiC whiskers or particulates, and B 4 C particulates added to the reaction mixture prior to combustion synthesis, was investigated next. It was found that, in general, reinforcements are heat sinks and limit the propagation of the reaction. Also, whiskers impede the flow of formed liquid to a larger extent than do particulates. Al 2 O 3 is inert and matrices reinforced with up to 2 wt. % Al 2 O 3 are composed essentially of Ni 3 Al grains. However, both B 4 C and SiC react with the Ni-Al matrix and lead to complex phases. In particular, B 4 C readily forms a Ni-Al-B liquid phase and disrupts dramatically the progress of the Ni 3 Al matrix synthesis. More... »

PAGES

1184-1192

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1557/jmr.1994.1184

DOI

http://dx.doi.org/10.1557/jmr.1994.1184

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1026717694


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Engineering", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0915", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Interdisciplinary Engineering", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Department of Chemical Engineering, University of Notre Dame, Notre Dame, Indiana 46556", 
          "id": "http://www.grid.ac/institutes/grid.131063.6", 
          "name": [
            "Department of Chemical Engineering, University of Notre Dame, Notre Dame, Indiana 46556"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lebrat", 
        "givenName": "Jean-Pascal", 
        "id": "sg:person.013524042652.77", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013524042652.77"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Department of Chemical Engineering, University of Notre Dame, Notre Dame, Indiana 46556", 
          "id": "http://www.grid.ac/institutes/grid.131063.6", 
          "name": [
            "Department of Chemical Engineering, University of Notre Dame, Notre Dame, Indiana 46556"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Varma", 
        "givenName": "Arvind", 
        "id": "sg:person.015311351425.35", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015311351425.35"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Center for Materials Science and Engineering, Department of Electrical Engineering, University of Notre Dame, Notre Dame, Indiana 46556", 
          "id": "http://www.grid.ac/institutes/grid.131063.6", 
          "name": [
            "Center for Materials Science and Engineering, Department of Electrical Engineering, University of Notre Dame, Notre Dame, Indiana 46556"
          ], 
          "type": "Organization"
        }, 
        "familyName": "McGinn", 
        "givenName": "Paul J.", 
        "id": "sg:person.013735066426.33", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013735066426.33"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1557/jmr.1990.2706", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044812551", 
          "https://doi.org/10.1557/jmr.1990.2706"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf03258828", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001750147", 
          "https://doi.org/10.1007/bf03258828"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02660854", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045380740", 
          "https://doi.org/10.1007/bf02660854"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1557/jmr.1990.1985", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030775045", 
          "https://doi.org/10.1557/jmr.1990.1985"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1557/jmr.1991.0355", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020608989", 
          "https://doi.org/10.1557/jmr.1991.0355"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1557/jmr.1990.2177", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047726518", 
          "https://doi.org/10.1557/jmr.1990.2177"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00740533", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1002233989", 
          "https://doi.org/10.1007/bf00740533"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf02666681", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005748463", 
          "https://doi.org/10.1007/bf02666681"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf03258543", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014775245", 
          "https://doi.org/10.1007/bf03258543"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/bf00742281", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045892875", 
          "https://doi.org/10.1007/bf00742281"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "1994-05", 
    "datePublishedReg": "1994-05-01", 
    "description": " Nickel aluminides exhibit limited ductility and toughness at room temperature. One way to improve these characteristics is by adding ceramic reinforcements to the matrix. In this paper, we have studied the combustion synthesis of Ni 3 Al and Ni 3 Al-matrix composites, using the self-propagating high-temperature synthesis (SHS) mode. First, studies of the Ni 3 Al synthesis were carried out by quenching the reaction during its progress, which revealed the mechanism of the synthesis. The influence of Al 2 O 3 and SiC whiskers or particulates, and B 4 C particulates added to the reaction mixture prior to combustion synthesis, was investigated next. It was found that, in general, reinforcements are heat sinks and limit the propagation of the reaction. Also, whiskers impede the flow of formed liquid to a larger extent than do particulates. Al 2 O 3 is inert and matrices reinforced with up to 2 wt. % Al 2 O 3 are composed essentially of Ni 3 Al grains. However, both B 4 C and SiC react with the Ni-Al matrix and lead to complex phases. In particular, B 4 C readily forms a Ni-Al-B liquid phase and disrupts dramatically the progress of the Ni 3 Al matrix synthesis. ", 
    "genre": "article", 
    "id": "sg:pub.10.1557/jmr.1994.1184", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1357547", 
        "issn": [
          "0884-2914", 
          "2044-5326"
        ], 
        "name": "Journal of Materials Research", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "5", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "9"
      }
    ], 
    "keywords": [
      "Al 2 O 3", 
      "combustion synthesis", 
      "self-propagating high-temperature synthesis (SHS) mode", 
      "Ni3Al-matrix composites", 
      "Al-matrix composites", 
      "Ni-Al matrix", 
      "ceramic reinforcement", 
      "Ni-Al", 
      "limited ductility", 
      "Ni 3 Al", 
      "SiC whiskers", 
      "heat sink", 
      "Al grains", 
      "SiC react", 
      "liquid phase", 
      "composites", 
      "synthesis mode", 
      "particulates", 
      "whiskers", 
      "room temperature", 
      "reinforcement", 
      "ductility", 
      "toughness", 
      "matrix", 
      "complex phase", 
      "Ni3Al", 
      "phase", 
      "liquid", 
      "flow", 
      "propagation", 
      "temperature", 
      "grains", 
      "wt", 
      "sink", 
      "mixture", 
      "large extent", 
      "mode", 
      "characteristics", 
      "influence", 
      "al", 
      "progress", 
      "synthesis", 
      "reaction", 
      "reaction mixture", 
      "study", 
      "mechanism", 
      "way", 
      "matrix synthesis", 
      "reacts", 
      "extent", 
      "mechanistic studies", 
      "disrupts", 
      "paper", 
      "Nickel aluminides exhibit limited ductility", 
      "aluminides exhibit limited ductility", 
      "exhibit limited ductility", 
      "Ni 3 Al-matrix composites", 
      "high-temperature synthesis (SHS) mode", 
      "Ni 3 Al synthesis", 
      "Al synthesis", 
      "O 3", 
      "Ni 3 Al grains", 
      "Ni 3 Al matrix synthesis", 
      "Al matrix synthesis"
    ], 
    "name": "Mechanistic studies in combustion synthesis of Ni3Al and Ni3Al-matrix composites", 
    "pagination": "1184-1192", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1026717694"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1557/jmr.1994.1184"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1557/jmr.1994.1184", 
      "https://app.dimensions.ai/details/publication/pub.1026717694"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-01-01T18:06", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/article/article_235.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1557/jmr.1994.1184"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1557/jmr.1994.1184'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1557/jmr.1994.1184'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1557/jmr.1994.1184'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1557/jmr.1994.1184'


 

This table displays all metadata directly associated to this object as RDF triples.

178 TRIPLES      22 PREDICATES      100 URIs      82 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1557/jmr.1994.1184 schema:about anzsrc-for:09
2 anzsrc-for:0915
3 schema:author N2247f343818b4cec89e18c6532eb091b
4 schema:citation sg:pub.10.1007/bf00740533
5 sg:pub.10.1007/bf00742281
6 sg:pub.10.1007/bf02660854
7 sg:pub.10.1007/bf02666681
8 sg:pub.10.1007/bf03258543
9 sg:pub.10.1007/bf03258828
10 sg:pub.10.1557/jmr.1990.1985
11 sg:pub.10.1557/jmr.1990.2177
12 sg:pub.10.1557/jmr.1990.2706
13 sg:pub.10.1557/jmr.1991.0355
14 schema:datePublished 1994-05
15 schema:datePublishedReg 1994-05-01
16 schema:description Nickel aluminides exhibit limited ductility and toughness at room temperature. One way to improve these characteristics is by adding ceramic reinforcements to the matrix. In this paper, we have studied the combustion synthesis of Ni 3 Al and Ni 3 Al-matrix composites, using the self-propagating high-temperature synthesis (SHS) mode. First, studies of the Ni 3 Al synthesis were carried out by quenching the reaction during its progress, which revealed the mechanism of the synthesis. The influence of Al 2 O 3 and SiC whiskers or particulates, and B 4 C particulates added to the reaction mixture prior to combustion synthesis, was investigated next. It was found that, in general, reinforcements are heat sinks and limit the propagation of the reaction. Also, whiskers impede the flow of formed liquid to a larger extent than do particulates. Al 2 O 3 is inert and matrices reinforced with up to 2 wt. % Al 2 O 3 are composed essentially of Ni 3 Al grains. However, both B 4 C and SiC react with the Ni-Al matrix and lead to complex phases. In particular, B 4 C readily forms a Ni-Al-B liquid phase and disrupts dramatically the progress of the Ni 3 Al matrix synthesis.
17 schema:genre article
18 schema:inLanguage en
19 schema:isAccessibleForFree false
20 schema:isPartOf N92bb3cd9f79344418d2d90dbcd569248
21 Nf86582a086cb46499aad51bf171db19c
22 sg:journal.1357547
23 schema:keywords Al 2 O 3
24 Al grains
25 Al matrix synthesis
26 Al synthesis
27 Al-matrix composites
28 Ni 3 Al
29 Ni 3 Al grains
30 Ni 3 Al matrix synthesis
31 Ni 3 Al synthesis
32 Ni 3 Al-matrix composites
33 Ni-Al
34 Ni-Al matrix
35 Ni3Al
36 Ni3Al-matrix composites
37 Nickel aluminides exhibit limited ductility
38 O 3
39 SiC react
40 SiC whiskers
41 al
42 aluminides exhibit limited ductility
43 ceramic reinforcement
44 characteristics
45 combustion synthesis
46 complex phase
47 composites
48 disrupts
49 ductility
50 exhibit limited ductility
51 extent
52 flow
53 grains
54 heat sink
55 high-temperature synthesis (SHS) mode
56 influence
57 large extent
58 limited ductility
59 liquid
60 liquid phase
61 matrix
62 matrix synthesis
63 mechanism
64 mechanistic studies
65 mixture
66 mode
67 paper
68 particulates
69 phase
70 progress
71 propagation
72 reaction
73 reaction mixture
74 reacts
75 reinforcement
76 room temperature
77 self-propagating high-temperature synthesis (SHS) mode
78 sink
79 study
80 synthesis
81 synthesis mode
82 temperature
83 toughness
84 way
85 whiskers
86 wt
87 schema:name Mechanistic studies in combustion synthesis of Ni3Al and Ni3Al-matrix composites
88 schema:pagination 1184-1192
89 schema:productId N43af91ff48e24c01baffe6297d694c57
90 N91af797206e94088a802cdb222d7d63f
91 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026717694
92 https://doi.org/10.1557/jmr.1994.1184
93 schema:sdDatePublished 2022-01-01T18:06
94 schema:sdLicense https://scigraph.springernature.com/explorer/license/
95 schema:sdPublisher N2cce48c821484200ae634a1c7134f7bf
96 schema:url https://doi.org/10.1557/jmr.1994.1184
97 sgo:license sg:explorer/license/
98 sgo:sdDataset articles
99 rdf:type schema:ScholarlyArticle
100 N2247f343818b4cec89e18c6532eb091b rdf:first sg:person.013524042652.77
101 rdf:rest Nbd78b293706547e188008008333ef2a4
102 N2cce48c821484200ae634a1c7134f7bf schema:name Springer Nature - SN SciGraph project
103 rdf:type schema:Organization
104 N301a1a699c4743a4889fea5171c4909e rdf:first sg:person.013735066426.33
105 rdf:rest rdf:nil
106 N43af91ff48e24c01baffe6297d694c57 schema:name dimensions_id
107 schema:value pub.1026717694
108 rdf:type schema:PropertyValue
109 N91af797206e94088a802cdb222d7d63f schema:name doi
110 schema:value 10.1557/jmr.1994.1184
111 rdf:type schema:PropertyValue
112 N92bb3cd9f79344418d2d90dbcd569248 schema:volumeNumber 9
113 rdf:type schema:PublicationVolume
114 Nbd78b293706547e188008008333ef2a4 rdf:first sg:person.015311351425.35
115 rdf:rest N301a1a699c4743a4889fea5171c4909e
116 Nf86582a086cb46499aad51bf171db19c schema:issueNumber 5
117 rdf:type schema:PublicationIssue
118 anzsrc-for:09 schema:inDefinedTermSet anzsrc-for:
119 schema:name Engineering
120 rdf:type schema:DefinedTerm
121 anzsrc-for:0915 schema:inDefinedTermSet anzsrc-for:
122 schema:name Interdisciplinary Engineering
123 rdf:type schema:DefinedTerm
124 sg:journal.1357547 schema:issn 0884-2914
125 2044-5326
126 schema:name Journal of Materials Research
127 schema:publisher Springer Nature
128 rdf:type schema:Periodical
129 sg:person.013524042652.77 schema:affiliation grid-institutes:grid.131063.6
130 schema:familyName Lebrat
131 schema:givenName Jean-Pascal
132 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013524042652.77
133 rdf:type schema:Person
134 sg:person.013735066426.33 schema:affiliation grid-institutes:grid.131063.6
135 schema:familyName McGinn
136 schema:givenName Paul J.
137 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013735066426.33
138 rdf:type schema:Person
139 sg:person.015311351425.35 schema:affiliation grid-institutes:grid.131063.6
140 schema:familyName Varma
141 schema:givenName Arvind
142 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015311351425.35
143 rdf:type schema:Person
144 sg:pub.10.1007/bf00740533 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002233989
145 https://doi.org/10.1007/bf00740533
146 rdf:type schema:CreativeWork
147 sg:pub.10.1007/bf00742281 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045892875
148 https://doi.org/10.1007/bf00742281
149 rdf:type schema:CreativeWork
150 sg:pub.10.1007/bf02660854 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045380740
151 https://doi.org/10.1007/bf02660854
152 rdf:type schema:CreativeWork
153 sg:pub.10.1007/bf02666681 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005748463
154 https://doi.org/10.1007/bf02666681
155 rdf:type schema:CreativeWork
156 sg:pub.10.1007/bf03258543 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014775245
157 https://doi.org/10.1007/bf03258543
158 rdf:type schema:CreativeWork
159 sg:pub.10.1007/bf03258828 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001750147
160 https://doi.org/10.1007/bf03258828
161 rdf:type schema:CreativeWork
162 sg:pub.10.1557/jmr.1990.1985 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030775045
163 https://doi.org/10.1557/jmr.1990.1985
164 rdf:type schema:CreativeWork
165 sg:pub.10.1557/jmr.1990.2177 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047726518
166 https://doi.org/10.1557/jmr.1990.2177
167 rdf:type schema:CreativeWork
168 sg:pub.10.1557/jmr.1990.2706 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044812551
169 https://doi.org/10.1557/jmr.1990.2706
170 rdf:type schema:CreativeWork
171 sg:pub.10.1557/jmr.1991.0355 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020608989
172 https://doi.org/10.1557/jmr.1991.0355
173 rdf:type schema:CreativeWork
174 grid-institutes:grid.131063.6 schema:alternateName Center for Materials Science and Engineering, Department of Electrical Engineering, University of Notre Dame, Notre Dame, Indiana 46556
175 Department of Chemical Engineering, University of Notre Dame, Notre Dame, Indiana 46556
176 schema:name Center for Materials Science and Engineering, Department of Electrical Engineering, University of Notre Dame, Notre Dame, Indiana 46556
177 Department of Chemical Engineering, University of Notre Dame, Notre Dame, Indiana 46556
178 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...