Advanced anode materials for sodium ion batteries: carbodiimides View Full Text


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Article Info

DATE

2017-03-03

AUTHORS

Aitor Eguia-Barrio, Elizabeth Castillo-Martinez, Xiaohui Liu, Richard Dronskowski, Luis Lezama, Michel Armand, Teofilo Rojo

ABSTRACT

TMNCN (where TM = Mn2+, Fe2+, Co2+ or Ni2+) have been recently proposed as electrochemically active materials for Na-ion insertion that operate via conversion reaction. Their electrochemical performance for Na-ion batteries is presented here with an emphasis on long-term cycling. With a very low voltage for Na insertion of ∼0.1V vs Na+/Na for MnNCN, the overpotential observed in batteries of MnNCN plays a very important role in their performance, evidencing big differences in the electrochemical performance between materials produced with different nano- and micrometer particle sizes evidenced by SEM images. A more suitable voltage for the conversion reaction accompanied by less overpotential is shown by FeNCN, CoNCN and NiNCN. Despite the lower reversible capacity achieved by FeNCN (450 mAh/g) in comparison with CoNCN and NiNCN in the first cycle; the smallest first-cycle irreversible capacity (220 mAh/g) and the lower voltage plateau (0.3 V vs Na+/Na) make FeNCN a good candidate as an anode material for sodium ion batteries. The voltages of conversion reaction are correlated with the calculated enthalpies of formation suggesting that thermodynamics dominates the observed electrochemical conversion reaction. More... »

PAGES

1165-1176

Identifiers

URI

http://scigraph.springernature.com/pub.10.1557/adv.2017.267

DOI

http://dx.doi.org/10.1557/adv.2017.267

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1084348808


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