Performance of chloroperoxidase stabilization in mesoporous sol-gel glass using In situ glucose oxidase peroxide generation View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2004-03

AUTHORS

Abhijeet Borole, Sheng Dai, Catherine L. Cheng, Miguel Rodriguez, Brian H. Davison

ABSTRACT

A unique mesoporous sol-gel glass possessing a highly ordered porous structure (with three pore sizes of about 50, 150, and 200 A diameter) was used as a support material for immobilization of the enzyme chloroperoxidase (CPO). CPO was bound onto the glass via a bifunctional ligand, trimethoxysilylpropanal. In situ production of the cosubstrate, H2O2, was achieved using glucose oxidase. Solvent stability in acetonitrile mixtures was enhanced when a pore size larger than the size of CPO was used (i.e., 200 A). From these results, it appears that the glass-enzyme complex developed through the present work can be used as high-performance biocatalysts for various chemical-processing applications, particularly in harsh conditions. More... »

PAGES

273-285

References to SciGraph publications

  • 1989-05. The activity of PEG-modified chymotrypsin in aqueous and organic media in BIOTECHNOLOGY LETTERS
  • 2003-01. Denaturation and Leaching Study of Horseradish Peroxidase Encapsulated in Sol-Gel Matrices in JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
  • 1997-08. Biocatalytic plastics as active and stable materials for biotransformations in NATURE BIOTECHNOLOGY
  • 1990-12. Immobilized lipase reactors for modification of fats and oils—A review in JOURNAL OF THE AMERICAN OIL CHEMISTS' SOCIETY
  • 1999-02-26. Immobilized Enzymes: Methods and Applications in BIOCATALYSIS - FROM DISCOVERY TO APPLICATION
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1385/abab:113:1-3:273

    DOI

    http://dx.doi.org/10.1385/abab:113:1-3:273

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1023862190

    PUBMED

    https://www.ncbi.nlm.nih.gov/pubmed/15054212


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    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1385/abab:113:1-3:273'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1385/abab:113:1-3:273'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1385/abab:113:1-3:273'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1385/abab:113:1-3:273'


     

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