A Novel Approach to the Synthesis of Optically Active Poly(β-hydroxy carbonyl)s by Aldol Polymerization Based on Mukaiyama Aldol Reaction View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

1999-11

AUTHORS

Kenichi Komura, Naoki Nishitani, Shinichi Itsuno

ABSTRACT

We have synthesized the poly(β-hydroxy ketone)s 1 and poly(β-hydroxy ester)s 2 by means of a novel polyaddition reaction of bis(triethylsilyl enol ether) 5 and bis(triethylsilyl ketene acetal) 7 with various dialdehydes 8–10, respectively. When chirally modified Lewis acids were used as catalyst for the polyaddition, optically active polymers were obtained.

PAGES

1045

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1295/polymj.31.1045

DOI

http://dx.doi.org/10.1295/polymj.31.1045

DIMENSIONS

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