Head-to-Head Polymers XXXV. Head-to-Head Poly(2-vinylnaphthalene) View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

1986-09

AUTHORS

Masato Nanasawa, Liping Hu, Otto Vogl

ABSTRACT

Head-to-head poly(2-vinylnaphthalene) was prepared in five steps from 2-naphthylacetic acid. The methyl ester was brominated with N-bromosuccinimide and 2(2-naphthyl)2-bromoacetate treated with a copper/zinc couple, which gave dimethyl 2,3-di(2-naphthyl)succinate in moderate yield. This compound was reduced with lithium aluminum hydride to 2,3-di(2-naphthyl)butanediol-1,4 and the hydroxyl groups replaced by bromine. 2,3-Di(2-naphthyl)-1,4-dibromobutane was subjected to the Yamamoto coupling polycondensation; head-to-head poly(2-vinylnaphthalene) was obtained in relatively low yield and of modest molecular weight. More... »

PAGES

681

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1295/polymj.18.681

DOI

http://dx.doi.org/10.1295/polymj.18.681

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1050930949


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