A New Class of Polymers: Starburst-Dendritic Macromolecules View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

1985-01

AUTHORS

D A Tomalia, H Baker, J Dewald, M Hall, G Kallos, S Martin, J Roeck, J Ryder, P Smith

ABSTRACT

This paper describes the first synthesis of a new class of topological macromolecules which we refer to as “starburst polymers.” The fundamental building blocks to this new polymer class are referred to as “dendrimers.” These dendrimers differ from classical monomers/oligomers by their extraordinary symmetry, high branching and maximized (telechelic) terminal functionality density. The dendrimers possess “reactive end groups” which allow (a) controlled moelcular weight building (monodispersity), (b) controlled branching (topology), and (c) versatility in design and modification of the terminal end groups. Dendrimer synthesis is accomplished by a variety of strategies involving “time sequenced propagation” techniques. The resulting dendrimers grow in a geometrically progressive fashion as shown: Chemically bridging these dendrimers leads to the new class of macromolecules—”starburst polymers” (e.g., (A)n, (B)n, or (C)n). More... »

PAGES

117

Journal

TITLE

Polymer Journal

ISSUE

1

VOLUME

17

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  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1295/polymj.17.117

    DOI

    http://dx.doi.org/10.1295/polymj.17.117

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1029771046


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