Immobilization of cesium from aqueous solution using nanoparticles of synthetic calcium phosphates View Full Text


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Article Info

DATE

2018-12

AUTHORS

Oksana Livitska, Nataliia Strutynska, Kateryna Loza, Oleg Prymak, Yuriy Prylutskyy, Olha Livitska, Matthias Epple, Nikolai Slobodyanik

ABSTRACT

The particularities of cesium incorporation into synthetic calcium phosphates with either apatite or whitlockite-type structures were investigated using the sorption process from aqueous solution and further heating to 700 °C. The nanoparticles for sorption were prepared by wet precipitation from aqueous solutions at a fixed molar ratio of Ca/P = 1.67 and two different ratios of CO32-/PO43- (0 or 1). The obtained substituted calcium phosphates and corresponding samples after the sorption of cesium from solutions with different molar concentrations (c(Cs+) = 0.05, 0.1 and 0.25 mol L-1) were characterized by powder X-ray diffraction, FTIR spectroscopy, scanning electron microscopy and elemental analysis. Based on the combination of X-ray diffraction and elemental analyses data for the powders after sorption, the cesium incorporated in the apatite- or whitlockite-type structures and its amount increased with its concentration in the initial solution. For sodium-containing calcium phosphate even minor content of Cs+ in its composition significantly changed the general principle of its transformation under annealing at 700 °C with the formation of a mixture of α-Ca3(PO4)2 and cesium-containing apatite-related phase. The obtained results indicate the perspective of using of complex substituted calcium phosphates nanoparticles for immobilization of cesium in the stable whitlockite- or apatite-type crystal materials. More... »

PAGES

87

Identifiers

URI

http://scigraph.springernature.com/pub.10.1186/s13065-018-0455-9

DOI

http://dx.doi.org/10.1186/s13065-018-0455-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1105812136

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/30043329


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44 schema:description The particularities of cesium incorporation into synthetic calcium phosphates with either apatite or whitlockite-type structures were investigated using the sorption process from aqueous solution and further heating to 700 °C. The nanoparticles for sorption were prepared by wet precipitation from aqueous solutions at a fixed molar ratio of Ca/P = 1.67 and two different ratios of CO<sub>3</sub><sup>2-</sup>/PO<sub>4</sub><sup>3-</sup> (0 or 1). The obtained substituted calcium phosphates and corresponding samples after the sorption of cesium from solutions with different molar concentrations (c(Cs<sup>+</sup>) = 0.05, 0.1 and 0.25 mol L<sup>-1</sup>) were characterized by powder X-ray diffraction, FTIR spectroscopy, scanning electron microscopy and elemental analysis. Based on the combination of X-ray diffraction and elemental analyses data for the powders after sorption, the cesium incorporated in the apatite- or whitlockite-type structures and its amount increased with its concentration in the initial solution. For sodium-containing calcium phosphate even minor content of Cs<sup>+</sup> in its composition significantly changed the general principle of its transformation under annealing at 700 °C with the formation of a mixture of α-Ca<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub> and cesium-containing apatite-related phase. The obtained results indicate the perspective of using of complex substituted calcium phosphates nanoparticles for immobilization of cesium in the stable whitlockite- or apatite-type crystal materials.
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