Acid-modified clinoptilolite as a support for palladium–copper complexes catalyzing carbon monoxide oxidation with air oxygen View Full Text


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Article Info

DATE

2017-03-27

AUTHORS

Tatyana L. Rakitskaya, Tatyana A. Kiose, Kristina O. Golubchik, Alim A. Ennan, Vitalia Y. Volkova

ABSTRACT

Samples of natural clinoptilolite were modified by an acid–thermal method at nitric acid concentrations of 0.25, 0.5, 1.0, and 3.0 M and a contact time of 30 min. A series of catalysts, K2PdCl4–Cu(NO3)2–KBr/S (S = 0.25H-CLI, 0.5H-CLI, 1H-CLI, and 3H-CLI) was obtained. All samples were investigated by X-ray phase and thermogravimetric analysis, FT-IR spectroscopy, water vapor ad/desorption and pH metric method. Besides, K2PdCl4–Cu(NO3)2–KBr/S samples were tested in the reaction of low-temperature carbon monoxide oxidation. It have been found that, owing to special physicochemical and structural-adsorption properties of 3H-CLI, it promotes formation of the palladium–copper catalyst providing carbon monoxide oxidation at the steady-state mode down to CO concentrations lower than its maximum permissible concentration at air relative humidity varied within a wide range. More... »

PAGES

28

Identifiers

URI

http://scigraph.springernature.com/pub.10.1186/s13065-017-0256-6

DOI

http://dx.doi.org/10.1186/s13065-017-0256-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1084252136

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/29086820


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