Ontology type: schema:ScholarlyArticle Open Access: True
2020-11-09
AUTHORSVladimir Yu. Osipov, Fedor M. Shakhov, Kirill V. Bogdanov, Kazuyuki Takai, Takuya Hayashi, François Treussart, Anna Baldycheva, Benjamin T. Hogan, Christian Jentgens
ABSTRACTWe demonstrate a high-pressure, high-temperature sintering technique to form nitrogen-vacancy-nitrogen centres in nanodiamonds. Polycrystalline diamond nanoparticle precursors, with mean size of 25 nm, are produced by the shock wave from an explosion. These nanoparticles are sintered in the presence of ethanol, at a pressure of 7 GPa and temperature of 1300 °C, to produce substantially larger (3–4 times) diamond crystallites. The recorded spectral properties demonstrate the improved crystalline quality. The types of defects present are also observed to change; the characteristic spectral features of nitrogen-vacancy and silicon-vacancy centres present for the precursor material disappear. Two new characteristic features appear: (1) paramagnetic substitutional nitrogen (P1 centres with spin ½) with an electron paramagnetic resonance characteristic triplet hyperfine structure due to the I = 1 magnetic moment of the nitrogen nuclear spin and (2) the green spectral photoluminescence signature of the nitrogen-vacancy-nitrogen centres. This production method is a strong alternative to conventional high-energy particle beam irradiation. It can be used to easily produce purely green fluorescing nanodiamonds with advantageous properties for optical biolabelling applications. More... »
PAGES209
http://scigraph.springernature.com/pub.10.1186/s11671-020-03433-7
DOIhttp://dx.doi.org/10.1186/s11671-020-03433-7
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1132457927
PUBMEDhttps://www.ncbi.nlm.nih.gov/pubmed/33169178
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/02",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/09",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Engineering",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0299",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Other Physical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0912",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Materials Engineering",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Ioffe Institute, Polytechnicheskaya 26, 194021, St. Petersburg, Russia",
"id": "http://www.grid.ac/institutes/grid.423485.c",
"name": [
"Ioffe Institute, Polytechnicheskaya 26, 194021, St. Petersburg, Russia"
],
"type": "Organization"
},
"familyName": "Osipov",
"givenName": "Vladimir Yu.",
"id": "sg:person.011737110415.43",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011737110415.43"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Ioffe Institute, Polytechnicheskaya 26, 194021, St. Petersburg, Russia",
"id": "http://www.grid.ac/institutes/grid.423485.c",
"name": [
"Ioffe Institute, Polytechnicheskaya 26, 194021, St. Petersburg, Russia"
],
"type": "Organization"
},
"familyName": "Shakhov",
"givenName": "Fedor M.",
"id": "sg:person.010775023623.54",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010775023623.54"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "ITMO University, Kronverksky 47, 197101, St. Petersburg, Russia",
"id": "http://www.grid.ac/institutes/grid.35915.3b",
"name": [
"ITMO University, Kronverksky 47, 197101, St. Petersburg, Russia"
],
"type": "Organization"
},
"familyName": "Bogdanov",
"givenName": "Kirill V.",
"id": "sg:person.016602056460.34",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016602056460.34"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Department of Chemical Science and Technology, Hosei University, 3-7-2, Kajino, Koganei, 184-8584, Tokyo, Japan",
"id": "http://www.grid.ac/institutes/grid.257114.4",
"name": [
"Department of Chemical Science and Technology, Hosei University, 3-7-2, Kajino, Koganei, 184-8584, Tokyo, Japan"
],
"type": "Organization"
},
"familyName": "Takai",
"givenName": "Kazuyuki",
"id": "sg:person.016341404751.21",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016341404751.21"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Faculty of Engineering, Shinshu University, 4-17-1 Wakasato, 380-8553, Nagano, Japan",
"id": "http://www.grid.ac/institutes/grid.263518.b",
"name": [
"Faculty of Engineering, Shinshu University, 4-17-1 Wakasato, 380-8553, Nagano, Japan"
],
"type": "Organization"
},
"familyName": "Hayashi",
"givenName": "Takuya",
"id": "sg:person.013233663042.24",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013233663042.24"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Universit\u00e9 Paris-Saclay, CNRS, ENS Paris-Saclay, CentraleSup\u00e9lec, LuMIn, 91190, Gif-sur-Yvette, France",
"id": "http://www.grid.ac/institutes/grid.494567.d",
"name": [
"Universit\u00e9 Paris-Saclay, CNRS, ENS Paris-Saclay, CentraleSup\u00e9lec, LuMIn, 91190, Gif-sur-Yvette, France"
],
"type": "Organization"
},
"familyName": "Treussart",
"givenName": "Fran\u00e7ois",
"id": "sg:person.0760437517.35",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0760437517.35"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "College of Engineering Mathematics and Physical Sciences, University of Exeter, EX4 4QF, Exeter, UK",
"id": "http://www.grid.ac/institutes/grid.8391.3",
"name": [
"College of Engineering Mathematics and Physical Sciences, University of Exeter, EX4 4QF, Exeter, UK"
],
"type": "Organization"
},
"familyName": "Baldycheva",
"givenName": "Anna",
"id": "sg:person.013313705771.67",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013313705771.67"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Optoelectronics and Measurement Techniques Research Unit, University of Oulu, 90570, Oulu, Finland",
"id": "http://www.grid.ac/institutes/grid.10858.34",
"name": [
"College of Engineering Mathematics and Physical Sciences, University of Exeter, EX4 4QF, Exeter, UK",
"Optoelectronics and Measurement Techniques Research Unit, University of Oulu, 90570, Oulu, Finland"
],
"type": "Organization"
},
"familyName": "Hogan",
"givenName": "Benjamin T.",
"id": "sg:person.015741765443.85",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015741765443.85"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Microdiamant AG, Kreuzlingerstrasse 1, 8574, Lengwil, Switzerland",
"id": "http://www.grid.ac/institutes/None",
"name": [
"Microdiamant AG, Kreuzlingerstrasse 1, 8574, Lengwil, Switzerland"
],
"type": "Organization"
},
"familyName": "Jentgens",
"givenName": "Christian",
"id": "sg:person.013673600314.78",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013673600314.78"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1007/978-3-642-20595-8_8",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1033619884",
"https://doi.org/10.1007/978-3-642-20595-8_8"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1186/s11671-019-3111-y",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1120376468",
"https://doi.org/10.1186/s11671-019-3111-y"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s1063783417060191",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1085966680",
"https://doi.org/10.1134/s1063783417060191"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s1063783418040236",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1103423845",
"https://doi.org/10.1134/s1063783418040236"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/978-1-4419-0531-4_6",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1051204479",
"https://doi.org/10.1007/978-1-4419-0531-4_6"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s0020168516040142",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1015232507",
"https://doi.org/10.1134/s0020168516040142"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/978-3-662-04548-0",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1006004391",
"https://doi.org/10.1007/978-3-662-04548-0"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/978-3-642-37490-6",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1012622297",
"https://doi.org/10.1007/978-3-642-37490-6"
],
"type": "CreativeWork"
}
],
"datePublished": "2020-11-09",
"datePublishedReg": "2020-11-09",
"description": "We demonstrate a high-pressure, high-temperature sintering technique to form nitrogen-vacancy-nitrogen centres in nanodiamonds. Polycrystalline diamond nanoparticle precursors, with mean size of 25\u00a0nm, are produced by the shock wave from an explosion. These nanoparticles are sintered in the presence of ethanol, at a pressure of 7\u00a0GPa and temperature of 1300\u00a0\u00b0C, to produce substantially larger (3\u20134 times) diamond crystallites. The recorded spectral properties demonstrate the improved crystalline quality. The types of defects present are also observed to change; the characteristic spectral features of nitrogen-vacancy and silicon-vacancy centres present for the precursor material disappear. Two new characteristic features appear: (1) paramagnetic substitutional nitrogen (P1 centres with spin \u00bd) with an electron paramagnetic resonance characteristic triplet hyperfine structure due to the I\u2009=\u20091 magnetic moment of the nitrogen nuclear spin and (2) the green spectral photoluminescence signature of the nitrogen-vacancy-nitrogen centres. This production method is a strong alternative to conventional high-energy particle beam irradiation. It can be used to easily produce purely green fluorescing nanodiamonds with advantageous properties for optical biolabelling applications.",
"genre": "article",
"id": "sg:pub.10.1186/s11671-020-03433-7",
"inLanguage": "en",
"isAccessibleForFree": true,
"isFundedItemOf": [
{
"id": "sg:grant.8435805",
"type": "MonetaryGrant"
},
{
"id": "sg:grant.5498346",
"type": "MonetaryGrant"
},
{
"id": "sg:grant.4576232",
"type": "MonetaryGrant"
}
],
"isPartOf": [
{
"id": "sg:journal.1037280",
"issn": [
"1931-7573",
"1556-276X"
],
"name": "Nanoscale Research Letters",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "1",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "15"
}
],
"keywords": [
"silicon-vacancy centers",
"nitrogen nuclear spin",
"particle beam irradiation",
"characteristic spectral features",
"improved crystalline quality",
"nanoparticle precursors",
"nuclear spins",
"photoluminescence signatures",
"hyperfine structure",
"magnetic moment",
"substitutional nitrogen",
"crystalline quality",
"nitrogen centers",
"nanodiamonds",
"beam irradiation",
"spectral features",
"new characteristic features",
"shock waves",
"advantageous properties",
"presence of ethanol",
"spectral properties",
"production methods",
"mean size",
"types of defects",
"diamond",
"triplet hyperfine structure",
"HPHT sintering",
"nanoparticles",
"strong alternative",
"spin",
"large diamonds",
"waves",
"properties",
"ethanol",
"irradiation",
"characteristic features",
"sintering",
"precursors",
"applications",
"moment",
"GPa",
"explosion",
"signatures",
"disappears",
"temperature",
"size",
"structure",
"center",
"technique",
"defects",
"nitrogen",
"features",
"pressure",
"alternative",
"method",
"quality",
"presence",
"types"
],
"name": "High-Quality Green-Emitting Nanodiamonds Fabricated by HPHT Sintering of Polycrystalline Shockwave Diamonds",
"pagination": "209",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1132457927"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1186/s11671-020-03433-7"
]
},
{
"name": "pubmed_id",
"type": "PropertyValue",
"value": [
"33169178"
]
}
],
"sameAs": [
"https://doi.org/10.1186/s11671-020-03433-7",
"https://app.dimensions.ai/details/publication/pub.1132457927"
],
"sdDataset": "articles",
"sdDatePublished": "2022-05-20T07:37",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220519/entities/gbq_results/article/article_864.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1186/s11671-020-03433-7"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1186/s11671-020-03433-7'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1186/s11671-020-03433-7'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1186/s11671-020-03433-7'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1186/s11671-020-03433-7'
This table displays all metadata directly associated to this object as RDF triples.
244 TRIPLES
22 PREDICATES
94 URIs
76 LITERALS
7 BLANK NODES