Formation of Monodisperse Carbon Spheres with Tunable Size via Triblock Copolymer-Assisted Synthesis and Their Capacitor Properties. View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2019-12

AUTHORS

Zhongguan Liang, Luomeng Zhang, Hao Liu, Jianping Zeng, Jianfei Zhou, Hongjian Li, Hui Xia

ABSTRACT

A facile hydrothermal polymerization method has been developed for the preparation of monodisperse carbon spheres (MCSs) using the triblock copolymer F108 as surfactant. The synthesis is based on the ammonia-catalyzed polymerization reaction between phenol and formaldehyde (PF). The resultant MCSs have a perfect spherical morphology, smooth surface, and high dispersity. The particle sizes can be tuned in a wide range of 500~2400 nm by adjusting the dosage of the PF precursor. The activated MCSs with suitable heteroatoms (N and O) doped and a large specific surface area (960 m2 g-1) were obtained. A high-performance electrode of electrical double-layer capacitors fabricated by those active material have an excellent specific capacitance (310 F g-1 at 0.5 A g-1) and outstanding cycling stability (92% capacitance retention after 10,000 cycles). This work provides a new opportunity for the fabrication of MCSs with potential applications. More... »

PAGES

124

Identifiers

URI

http://scigraph.springernature.com/pub.10.1186/s11671-019-2952-8

DOI

http://dx.doi.org/10.1186/s11671-019-2952-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1113182400

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/30945028


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