Layer-dependent morphologies of silver on n-layer graphene View Full Text


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Article Info

DATE

2012-12

AUTHORS

Cheng-wen Huang, Hsing-Ying Lin, Chen-Han Huang, Ren-Jye Shiue, Wei-Hua Wang, Chih-Yi Liu, Hsiang-Chen Chui

ABSTRACT

The distributions of sizes of silver nanoparticles that were deposited on monolayer, bilayer, and trilayer graphene films were observed. Deposition was carried out by thermal evaporation and the graphene films, placed on SiO2/Si substrates, were obtained by the mechanical splitting of graphite. Before the deposition, optical microscopy and Raman spectroscopy were utilized to identify the number of the graphene layers. After the deposition, scanning electron microscopy was used to observe the morphologies of the particles. Systematic analysis revealed that the average sizes of the nanoparticles increased with the number of graphene layers. The density of nanoparticles decreased as the number of graphene layers increased, revealing a large variation in the surface diffusion strength of nanoparticles on the different substrates. The mechanisms of formation of these layer-dependent morphologies of silver on n-layer graphene are related to the surface free energy and surface diffusion of the n-layer graphene. The effect of the substrate such as SiO2/Si was investigated by fabricating suspended graphene, and the size and density were similar to those of supported graphene. Based on a comparison of the results, the different morphologies of the silver nanoparticles on different graphene layers were theorized to be caused only by the variation of the diffusion barriers with the number of layers of graphene. More... »

PAGES

618

References to SciGraph publications

  • 2012-12. Observation of strain effect on the suspended graphene by polarized Raman spectroscopy in NANOSCALE RESEARCH LETTERS
  • 2007-03. The rise of graphene in NATURE MATERIALS
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1186/1556-276x-7-618

    DOI

    http://dx.doi.org/10.1186/1556-276x-7-618

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    PUBMED

    https://www.ncbi.nlm.nih.gov/pubmed/23140587


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