Spectrophotometric Study of Adduct Formation Between [Co(Salen)PPh3]ClO4.H2O and [Co(7,7'-Dimethylsalen)PPh3]ClO4.H2O with Amines Donors in Acetonitrile View Full Text


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Article Info

DATE

2010

AUTHORS

Mahmood Niad, Khosro Mohammadi, Mozaffar Asadi

ABSTRACT

The equilibrium quotient of the adduct formation of [Co(Salen)PPh 3 ]ClO 4 .H 2 O and [Co(7,7'-dimethylSalen)PPh 3 ]ClO 4 .H 2 O, as acceptor with amines donors are studied by spectrophotometer. Thermodynamics of these pentacoordinate cobalt(III) Schiff-base complexes have been examined with n -butylamine, sec -butylamine, tert -butylamine, benzylamine and diethylamine in constant ionic strength of 0.1 M sodium perchlorate and acetonitrile solvent at room temperature. We aimed to investigate the effects of different electronic and steric situations of donor and acceptor by comparing their equilibrium quotient for any adduct. More... »

PAGES

1421-1425

Identifiers

URI

http://scigraph.springernature.com/pub.10.1155/2010/320126

DOI

http://dx.doi.org/10.1155/2010/320126

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1049256581


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