Statistical mechanical approach to secondary processes and structural relaxation in glasses and glass formers View Full Text


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Article Info

DATE

2011-09

AUTHORS

A. Crisanti, L. Leuzzi, M. Paoluzzi

ABSTRACT

The interrelation of dynamic processes active on separated time-scales in glasses and viscous liquids is investigated using a model displaying two time-scale bifurcations both between fast and secondary relaxation and between secondary and structural relaxation. The study of the dynamics allows for predictions on the system relaxation above the temperature of dynamic arrest in the mean-field approximation, that are compared with the outcomes of the equations of motion directly derived within the Mode Coupling Theory (MCT) for under-cooled viscous liquids. By varying the external thermodynamic parameters, a wide range of phenomenology can be represented, from a very clear separation of structural and secondary peak in the susceptibility loss to excess wing structures. More... »

PAGES

98

References to SciGraph publications

  • 1992-10. The sphericalp-spin interaction spin glass model: the statics in ZEITSCHRIFT FÜR PHYSIK B CONDENSED MATTER
  • 1993-06. The sphericalp-spin interaction spin-glass model in ZEITSCHRIFT FÜR PHYSIK B CONDENSED MATTER
  • 2010-01. A universal origin for secondary relaxations in supercooled liquids and structural glasses in NATURE PHYSICS
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1140/epje/i2011-11098-3

    DOI

    http://dx.doi.org/10.1140/epje/i2011-11098-3

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    PUBMED

    https://www.ncbi.nlm.nih.gov/pubmed/21947889


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