Structure of polymer micelles close to the solid interface View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2005-02

AUTHORS

M. Wolff, A. Magerl, H. Zabel

ABSTRACT

Block copolymers are widely used in industry. For scientific interests their aqueous solutions offer a model system for the investigation of crystallisation as the macromolecules agglomerate for elevated concentrations into micelles, which crystallise when a critical volume fraction is reached. We report on grazing incidence small angle neutron scattering (GISANS) or near surface small angle neutron scattering (NS-SANS) as an experimental tool to investigate the micelle crystallisation close to interfaces with different chemical termination. We find that in general crystallization is suppressed at a repulsive surface and favoured at an attractive one. Furthermore we show that the crystallization close the interface can be controlled by the micelle stability, resulting from the different composition and length of the monomers. The effect of the interface is found more important for a high micelle stability, whereas for a low stability it is shadowed by adsorbed monomers. More... »

PAGES

141-145

Identifiers

URI

http://scigraph.springernature.com/pub.10.1140/epje/e2005-00015-0

DOI

http://dx.doi.org/10.1140/epje/e2005-00015-0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1002570515

PUBMED

https://www.ncbi.nlm.nih.gov/pubmed/15729505


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Ruhr University Bochum", 
          "id": "https://www.grid.ac/institutes/grid.5570.7", 
          "name": [
            "Institut Laue-Langevin, BP 156, 38042, Grenoble, France", 
            "Lehrstuhl f\u00fcr Festk\u00f6rperphysik, Ruhr-Universit\u00e4t Bochum, 44780, Bochum, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Wolff", 
        "givenName": "M.", 
        "id": "sg:person.0771136654.41", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0771136654.41"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "University of Erlangen-Nuremberg", 
          "id": "https://www.grid.ac/institutes/grid.5330.5", 
          "name": [
            "Lehrstuhl f\u00fcr Kristallographie und Strukturphysik, Universit\u00e4t Erlangen-N\u00fcrnberg, 91058, Erlangen, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Magerl", 
        "givenName": "A.", 
        "id": "sg:person.01120550476.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01120550476.01"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Ruhr University Bochum", 
          "id": "https://www.grid.ac/institutes/grid.5570.7", 
          "name": [
            "Lehrstuhl f\u00fcr Festk\u00f6rperphysik, Ruhr-Universit\u00e4t Bochum, 44780, Bochum, Germany"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zabel", 
        "givenName": "H.", 
        "id": "sg:person.01151265267.43", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01151265267.43"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1038/nature01775", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011592620", 
          "https://doi.org/10.1038/nature01775"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nature01775", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011592620", 
          "https://doi.org/10.1038/nature01775"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1054/bjoc.2001.2165", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1024230968", 
          "https://doi.org/10.1054/bjoc.2001.2165"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat997", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032148867", 
          "https://doi.org/10.1038/nmat997"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat997", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032148867", 
          "https://doi.org/10.1038/nmat997"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.physb.2004.11.027", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1032562811"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/sj.gt.3301052", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033516229", 
          "https://doi.org/10.1038/sj.gt.3301052"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/sj.gt.3301052", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033516229", 
          "https://doi.org/10.1038/sj.gt.3301052"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/b002362k", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037370174"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0378-5173(84)90022-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046842133"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0378-5173(84)90022-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046842133"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/1099-1581(200101/02)12:1/2<2::aid-pat946>3.0.co;2-e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049278235"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/j100157a064", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055655610"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la026745v", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056144971"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/la026745v", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056144971"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma9701088", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056207087"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma9701088", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056207087"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma980705+", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056208697"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ma980705+", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056208697"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrev.95.359", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060462647"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrev.95.359", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060462647"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physreve.66.021403", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060728836"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physreve.66.021403", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060728836"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.92.255501", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060828553"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1103/physrevlett.92.255501", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1060828553"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2005-02", 
    "datePublishedReg": "2005-02-01", 
    "description": "Block copolymers are widely used in industry. For scientific interests their aqueous solutions offer a model system for the investigation of crystallisation as the macromolecules agglomerate for elevated concentrations into micelles, which crystallise when a critical volume fraction is reached. We report on grazing incidence small angle neutron scattering (GISANS) or near surface small angle neutron scattering (NS-SANS) as an experimental tool to investigate the micelle crystallisation close to interfaces with different chemical termination. We find that in general crystallization is suppressed at a repulsive surface and favoured at an attractive one. Furthermore we show that the crystallization close the interface can be controlled by the micelle stability, resulting from the different composition and length of the monomers. The effect of the interface is found more important for a high micelle stability, whereas for a low stability it is shadowed by adsorbed monomers.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1140/epje/e2005-00015-0", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1356903", 
        "issn": [
          "1292-8941", 
          "1292-895X"
        ], 
        "name": "The European Physical Journal E", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "16"
      }
    ], 
    "name": "Structure of polymer micelles close to the solid interface", 
    "pagination": "141-145", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "0c3d157c464c35993199a58f2aec6b552fc279bf6075bea7642e23b60c0ddc7e"
        ]
      }, 
      {
        "name": "pubmed_id", 
        "type": "PropertyValue", 
        "value": [
          "15729505"
        ]
      }, 
      {
        "name": "nlm_unique_id", 
        "type": "PropertyValue", 
        "value": [
          "101126530"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1140/epje/e2005-00015-0"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1002570515"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1140/epje/e2005-00015-0", 
      "https://app.dimensions.ai/details/publication/pub.1002570515"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T21:49", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8687_00000579.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1140%2Fepje%2Fe2005-00015-0"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1140/epje/e2005-00015-0'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1140/epje/e2005-00015-0'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1140/epje/e2005-00015-0'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1140/epje/e2005-00015-0'


 

This table displays all metadata directly associated to this object as RDF triples.

136 TRIPLES      21 PREDICATES      44 URIs      21 LITERALS      9 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1140/epje/e2005-00015-0 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N01b14b4cc93f406b82b0650a4969c05e
4 schema:citation sg:pub.10.1038/nature01775
5 sg:pub.10.1038/nmat997
6 sg:pub.10.1038/sj.gt.3301052
7 sg:pub.10.1054/bjoc.2001.2165
8 https://doi.org/10.1002/1099-1581(200101/02)12:1/2<2::aid-pat946>3.0.co;2-e
9 https://doi.org/10.1016/0378-5173(84)90022-x
10 https://doi.org/10.1016/j.physb.2004.11.027
11 https://doi.org/10.1021/j100157a064
12 https://doi.org/10.1021/la026745v
13 https://doi.org/10.1021/ma9701088
14 https://doi.org/10.1021/ma980705+
15 https://doi.org/10.1039/b002362k
16 https://doi.org/10.1103/physrev.95.359
17 https://doi.org/10.1103/physreve.66.021403
18 https://doi.org/10.1103/physrevlett.92.255501
19 schema:datePublished 2005-02
20 schema:datePublishedReg 2005-02-01
21 schema:description Block copolymers are widely used in industry. For scientific interests their aqueous solutions offer a model system for the investigation of crystallisation as the macromolecules agglomerate for elevated concentrations into micelles, which crystallise when a critical volume fraction is reached. We report on grazing incidence small angle neutron scattering (GISANS) or near surface small angle neutron scattering (NS-SANS) as an experimental tool to investigate the micelle crystallisation close to interfaces with different chemical termination. We find that in general crystallization is suppressed at a repulsive surface and favoured at an attractive one. Furthermore we show that the crystallization close the interface can be controlled by the micelle stability, resulting from the different composition and length of the monomers. The effect of the interface is found more important for a high micelle stability, whereas for a low stability it is shadowed by adsorbed monomers.
22 schema:genre research_article
23 schema:inLanguage en
24 schema:isAccessibleForFree false
25 schema:isPartOf Na37785199a1041f98711d012466bcb3b
26 Nb509162a0dd24054be79ca559f2e1610
27 sg:journal.1356903
28 schema:name Structure of polymer micelles close to the solid interface
29 schema:pagination 141-145
30 schema:productId N22e9a4b90a5648fd94d56bb03c24f0cf
31 N47565f1b25b84c338f4dcb243755e520
32 N4de94f58718c4f6188f39faaaf716f02
33 N6d02f1c9cf0c47ec9c930f71b00de9aa
34 Nd46f334a84484e828e3389cac3c86520
35 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002570515
36 https://doi.org/10.1140/epje/e2005-00015-0
37 schema:sdDatePublished 2019-04-10T21:49
38 schema:sdLicense https://scigraph.springernature.com/explorer/license/
39 schema:sdPublisher Ndbeb8437089848c18887ada7de4364d8
40 schema:url http://link.springer.com/10.1140%2Fepje%2Fe2005-00015-0
41 sgo:license sg:explorer/license/
42 sgo:sdDataset articles
43 rdf:type schema:ScholarlyArticle
44 N01b14b4cc93f406b82b0650a4969c05e rdf:first sg:person.0771136654.41
45 rdf:rest N28da9b027a6940149b0cb8291ea169af
46 N22e9a4b90a5648fd94d56bb03c24f0cf schema:name pubmed_id
47 schema:value 15729505
48 rdf:type schema:PropertyValue
49 N28da9b027a6940149b0cb8291ea169af rdf:first sg:person.01120550476.01
50 rdf:rest Nd57b1b230f80455aaee892f8bd8530a9
51 N47565f1b25b84c338f4dcb243755e520 schema:name readcube_id
52 schema:value 0c3d157c464c35993199a58f2aec6b552fc279bf6075bea7642e23b60c0ddc7e
53 rdf:type schema:PropertyValue
54 N4de94f58718c4f6188f39faaaf716f02 schema:name dimensions_id
55 schema:value pub.1002570515
56 rdf:type schema:PropertyValue
57 N6d02f1c9cf0c47ec9c930f71b00de9aa schema:name doi
58 schema:value 10.1140/epje/e2005-00015-0
59 rdf:type schema:PropertyValue
60 Na37785199a1041f98711d012466bcb3b schema:volumeNumber 16
61 rdf:type schema:PublicationVolume
62 Nb509162a0dd24054be79ca559f2e1610 schema:issueNumber 2
63 rdf:type schema:PublicationIssue
64 Nd46f334a84484e828e3389cac3c86520 schema:name nlm_unique_id
65 schema:value 101126530
66 rdf:type schema:PropertyValue
67 Nd57b1b230f80455aaee892f8bd8530a9 rdf:first sg:person.01151265267.43
68 rdf:rest rdf:nil
69 Ndbeb8437089848c18887ada7de4364d8 schema:name Springer Nature - SN SciGraph project
70 rdf:type schema:Organization
71 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
72 schema:name Chemical Sciences
73 rdf:type schema:DefinedTerm
74 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
75 schema:name Physical Chemistry (incl. Structural)
76 rdf:type schema:DefinedTerm
77 sg:journal.1356903 schema:issn 1292-8941
78 1292-895X
79 schema:name The European Physical Journal E
80 rdf:type schema:Periodical
81 sg:person.01120550476.01 schema:affiliation https://www.grid.ac/institutes/grid.5330.5
82 schema:familyName Magerl
83 schema:givenName A.
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01120550476.01
85 rdf:type schema:Person
86 sg:person.01151265267.43 schema:affiliation https://www.grid.ac/institutes/grid.5570.7
87 schema:familyName Zabel
88 schema:givenName H.
89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01151265267.43
90 rdf:type schema:Person
91 sg:person.0771136654.41 schema:affiliation https://www.grid.ac/institutes/grid.5570.7
92 schema:familyName Wolff
93 schema:givenName M.
94 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0771136654.41
95 rdf:type schema:Person
96 sg:pub.10.1038/nature01775 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011592620
97 https://doi.org/10.1038/nature01775
98 rdf:type schema:CreativeWork
99 sg:pub.10.1038/nmat997 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032148867
100 https://doi.org/10.1038/nmat997
101 rdf:type schema:CreativeWork
102 sg:pub.10.1038/sj.gt.3301052 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033516229
103 https://doi.org/10.1038/sj.gt.3301052
104 rdf:type schema:CreativeWork
105 sg:pub.10.1054/bjoc.2001.2165 schema:sameAs https://app.dimensions.ai/details/publication/pub.1024230968
106 https://doi.org/10.1054/bjoc.2001.2165
107 rdf:type schema:CreativeWork
108 https://doi.org/10.1002/1099-1581(200101/02)12:1/2<2::aid-pat946>3.0.co;2-e schema:sameAs https://app.dimensions.ai/details/publication/pub.1049278235
109 rdf:type schema:CreativeWork
110 https://doi.org/10.1016/0378-5173(84)90022-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1046842133
111 rdf:type schema:CreativeWork
112 https://doi.org/10.1016/j.physb.2004.11.027 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032562811
113 rdf:type schema:CreativeWork
114 https://doi.org/10.1021/j100157a064 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055655610
115 rdf:type schema:CreativeWork
116 https://doi.org/10.1021/la026745v schema:sameAs https://app.dimensions.ai/details/publication/pub.1056144971
117 rdf:type schema:CreativeWork
118 https://doi.org/10.1021/ma9701088 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056207087
119 rdf:type schema:CreativeWork
120 https://doi.org/10.1021/ma980705+ schema:sameAs https://app.dimensions.ai/details/publication/pub.1056208697
121 rdf:type schema:CreativeWork
122 https://doi.org/10.1039/b002362k schema:sameAs https://app.dimensions.ai/details/publication/pub.1037370174
123 rdf:type schema:CreativeWork
124 https://doi.org/10.1103/physrev.95.359 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060462647
125 rdf:type schema:CreativeWork
126 https://doi.org/10.1103/physreve.66.021403 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060728836
127 rdf:type schema:CreativeWork
128 https://doi.org/10.1103/physrevlett.92.255501 schema:sameAs https://app.dimensions.ai/details/publication/pub.1060828553
129 rdf:type schema:CreativeWork
130 https://www.grid.ac/institutes/grid.5330.5 schema:alternateName University of Erlangen-Nuremberg
131 schema:name Lehrstuhl für Kristallographie und Strukturphysik, Universität Erlangen-Nürnberg, 91058, Erlangen, Germany
132 rdf:type schema:Organization
133 https://www.grid.ac/institutes/grid.5570.7 schema:alternateName Ruhr University Bochum
134 schema:name Institut Laue-Langevin, BP 156, 38042, Grenoble, France
135 Lehrstuhl für Festkörperphysik, Ruhr-Universität Bochum, 44780, Bochum, Germany
136 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...