Photodissociation and photoionization of sodium coated C \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$_\mathsf{60}$\end{document} clusters View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2003-07

AUTHORS

M. Pellarin, E. Cottancin, J. Lermé, J.L. Vialle, M. Broyer, F. Tournus, B. Masenelli, P. Mélinon

ABSTRACT

(C60)mNan clusters are produced in a tandem laser vaporization source and analyzed by photoionization and photofragmentation time-of-flight mass spectroscopy. At low sodium coverage, the special behavior of (C60)m=1,2Nan clusters \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$(n\leq 6m)$\end{document} is consistent with a significant electron transfer from the first six adsorbed atoms towards each of the C60 fullerenes and an ionic-like bonding in this size range. However, the stability of the (C60)Na3+ cation is found much more pronounced than the one of (C60)Na7+ predicted to be a magic size under the hypothesis of a full charge transfer from the metal atoms to the C60 molecule. When more sodium atoms are present, metal-metal bonds tend to become preponderant and control the cluster properties. Relative to the number of sodium atoms, an odd-even alternation in their stability is explained by the high dissociation rates for even-numbered clusters. The even clusters evaporate neutral sodium atoms whereas odd ones prefer to evaporate Na2 molecules. The hypotheses for the growth of a sodium droplet that does not wet the fullerene surface or for the formation of a concentric metallic layer are discussed in the light of this study. More... »

PAGES

31-40

References to SciGraph publications

  • 1997-03. Optical response of cesium coated C60 in ZEITSCHRIFT FÜR PHYSIK D ATOMS,MOLECULES AND CLUSTERS
  • 2002-12. Shell structure of cesium layer covering the C fullerene core in THE EUROPEAN PHYSICAL JOURNAL D
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1140/epjd/e2003-00216-4

    DOI

    http://dx.doi.org/10.1140/epjd/e2003-00216-4

    DIMENSIONS

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