Electric dipole moments and conformations of isolated peptides View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2002-09

AUTHORS

R. Antoine, I. Compagnon, D. Rayane, M. Broyer, Ph. Dugourd, G. Breaux, F.C. Hagemeister, D. Pippen, R.R. Hudgins, M.F. Jarrold

ABSTRACT

The electric dipole moments of the isolated amino acid tryptophan and small glycine-based peptides (WGn, n = 1-5, W = tryptophan, G = glycine) have been measured by deflection of a molecular beam in an inhomogeneous electric field. The measurements are compared to the results of ab initio calculations and Monte-Carlo simulations. The conformation and the flexibility of the peptides, at different temperatures, are discussed. The WGn peptides are much more floppy than an isolated tryptophan, even a single glycine is enough to make the peptide floppy on the timescale of the electric deflection measurements. More... »

PAGES

583-587

Identifiers

URI

http://scigraph.springernature.com/pub.10.1140/epjd/e2002-00149-4

DOI

http://dx.doi.org/10.1140/epjd/e2002-00149-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1045632295


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