Magnetic behaviour of polyfluoroacridine-based organic molecular materials View Full Text


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Article Info

DATE

2010-02

AUTHORS

P. Campiglio, M. Campione, F. Canepa, C. Canevali, M. R. Cimberle, C. Fanciulli, L. Miozzo, M. Moret, A. Papagni, S. Rizzato, A. Sassella

ABSTRACT

The solid state magnetic properties of two new molecular organic materials based on polyfluoro- acridines functionalised with the 2,2,6,6-tetramethyl piperidine-1-oxyl radical (TEMPO) have been analyzed. After a first characterisation of the two materials by electron paramagnetic resonance and by X-ray diffraction, magnetisation measurements were performed from room temperature down to 2 K and the paramagnetic behaviour due to the unpaired spin on the radical TEMPO observed. Both compounds show some ferro-magnetic interactions down to 40 K, while at lower temperatures an antiferro-magnetic contribution switches on, possibly related to the reduction of intermolecular distances. More... »

PAGES

495-501

References to SciGraph publications

  • 2009-09. Spin routes in organic semiconductors in NATURE MATERIALS
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1140/epjb/e2010-00029-2

    DOI

    http://dx.doi.org/10.1140/epjb/e2010-00029-2

    DIMENSIONS

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