Effect of Crosslinking Agent Length on the Transport Properties of Polydecylmethylsiloxane-Based Membranes View Full Text


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Article Info

DATE

2020-09-30

AUTHORS

I. L. Borisov, E. A. Grushevenko, A. V. Volkov

ABSTRACT

The effect of crosslinking agent length on transport properties of membranes based on polydecylmethylsiloxane (PDecMS) has been studied. Dense PDecMS membranes reinforced with a stainless-steel grid and crosslinked with either 1,7-octadiene or vinyl-terminated polydimethylsiloxane (Mn = 500 g/mol) have been synthesized. The permeability of light hydrocarbons (methane, propane, n-butane) and separation characteristics of the membranes have been studied using an eight-component model mixture simulating the composition of the associated gas of an oil field. It was first found that crosslinking agent length has a significant effect on the selectivity of PDecMS-based membranes. Short crosslinking with 1,7-octadiene provides high gas permeability selectivities both in the case of permeability of individual gases and in the separation of a gas mixture. More... »

PAGES

318-324

References to SciGraph publications

  • 2019-03. Prospects of Membrane Science Development in MEMBRANES AND MEMBRANE TECHNOLOGIES
  • 2019-11. High-Selectivity Pervaporation Membranes for 1-Butanol Removal from Wastewater in RUSSIAN JOURNAL OF APPLIED CHEMISTRY
  • 2020-01. Separation of C1–C4 Hydrocarbon Mixtures Using Fe-Containing Siloxane Composition in MEMBRANES AND MEMBRANE TECHNOLOGIES
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    http://scigraph.springernature.com/pub.10.1134/s2517751620050030

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    http://dx.doi.org/10.1134/s2517751620050030

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