Combustion Synthesis of Membranes for Steam Reforming of Dimethyl Ether View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-03

AUTHORS

V. I. Uvarov, V. E. Loryan, S. V. Uvarov, V. S. Shustov, M. V. Tsodikov, A. S. Fedotov, D. O. Antonov, M. I. Alymov

ABSTRACT

We have developed a new generation of porous metal-ceramic membranes by using self-propagating high-temperature synthesis in vacuum on the basis of a mixture of a nickel powder (average particle size of 100 μm), cobalt oxide powder (average particle size of 10–15 nm), and aluminum powder (average particle size of 5–10 μm). In combustion synthesis, a membrane frame is formed from large particle fractions with open pores with size of 2.6–5.1 μm, so that it leads to an increase in membrane permeability and to a large consumption of the substrate. The synthesis thus produces porous metal-ceramic catalytically active membranes containing nanoparticles of nickel and cobalt in surface pore layers with size of 10–20 nm. The complete conversion of dimethyl ether is achieved at 450°C, producing synthesis gas and ultrahigh-purity hydrogen. More... »

PAGES

329-333

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s2075113318020302

DOI

http://dx.doi.org/10.1134/s2075113318020302

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1103602076


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