The effect of the nature of binary water–organic solvents on thermodynamic characteristics of adsorption of aromatic compounds on hyper-cross-linked polystyrene View Full Text


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Article Info

DATE

2016-11

AUTHORS

B. R. Saifutdinov

ABSTRACT

Using high-performance liquid chromatography under conditions close to equilibrium, adsorption has been investigated for a series of aromatic compounds from water–acetonitrile, water–methanol, and water–isopropyl alcohol solutions on hyper-cross-linked polystyrene with the degree of cross linking of 500%. The principles of the effect of the nature of binary water–organic solvents on thermodynamic characteristics of adsorption of the studied substances on hyper-cross-linked polystyrene have been determined. The role of intermolecular interactions, which are realized in bulk solution and interface, in the adsorption of aromatic compounds from their maximum diluted water–organic solutions on hyper-cross-linked polystyrene has been discussed. The compensation effect upon adsorption on hyper-cross-linked polystyrene individually from water–acetonitrile solution and various water–alcohol solutions has been discovered. The existence of linear dependences between the differences of Gibbs energy upon adsorption from water–organic solutions on hyper-cross-linked polystyrene has been shown. More... »

PAGES

979-985

References to SciGraph publications

  • 2010-01. Hypercrosslinked polystyrene networks with ultimate degrees of crosslinking and their sorption activity in RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
  • 2014-04-05. Methanol and acetonitrile associates in aqueous and chloroform solutions according to 1H NMR spectroscopic data in RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
  • 2014-10-30. Thermodynamics Study of Solvent Adsorption on Octadecyl-Modified Silica in CHROMATOGRAPHIA
  • 2011-01-08. Spectral-chemometric and quantum-chemical study of the water-acetonitrile system in JOURNAL OF ANALYTICAL CHEMISTRY
  • 2015-11-04. Selective adsorption of organic compounds from solutions on hyper-cross-linked polystyrenes with ultimate degrees of cross linking in PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES
  • 2014-11-05. Sorption concentration of phenylcarboxylic acids (biomarkers of sepsis) from standard test solutions on hyper-cross-linked polystyrene in PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES
  • 2014-12. Medium-property relationships and compensation effect in the adsorption of heteroaromatic compounds from aqueous acetonitrile solutions in RUSSIAN CHEMICAL BULLETIN
  • 2015-06. Thermodynamics of liquid-phase adsorption on hypercrosslinked polystyrene networks with ultimate degrees of crosslinking in DOKLADY PHYSICAL CHEMISTRY
  • 2013-11-07. Effect of the nature of binary water-organic solvents on the thermodynamic characteristics of adsorption of certain 1,3,4-oxadiazoles and 1,2,4,5-tetrazines on phenyl-bonded silica gel in RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
  • 2013-02-03. On the interrelation between the distribution constant and the retention factor in liquid chromatography in RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
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