The Effect of Star-Shaped Oligothiophenes with a Carbazole Core on Their Structural and Optical Properties View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-07

AUTHORS

A. V. Bakirov, A. N. Solodukhin, Yu. N. Luponosov, E. A. Svidchenko, M. A. Obrezkova, S. M. Peregudova, M. A. Shcherbina, S. A. Ponomarenko, S. N. Chvalun

ABSTRACT

A comparative analysis of the structure and properties of donor–acceptor star-shaped compounds based on oligothiophene with electron-withdrawing dicyanovinyl groups and a different electron-donating branching center—planar 9-phenyl-9H-carbazole and propeller-shaped triphenylamine—has been carried out. It is shown that the absorption maxima in the spectra of 9-phenyl-9H-carbazole derivatives shift to shorter wavelengths, the HOMO energy decreases, and the LUMO energy increases. Moreover, in contrast to propeller-shaped triphenylamine-based compounds, which do not form ordered states, the T-shaped branched molecules based on carbazole form highly ordered crystal structures with different symmetry. More... »

PAGES

385-394

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s199507801704005x

DOI

http://dx.doi.org/10.1134/s199507801704005x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1101370765


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