Kinetics of Thermal Decomposition of 2,4-Bis(N,N-Dimethylamino)-6-Trinitromethyl-1,3,5-Triazine View Full Text


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Article Info

DATE

2019-07

AUTHORS

B. L. Korsunskiy, T. S. Larikova, V. V. Zakharov, V. V. Nedel’ko, N. V. Chukanov, A. V. Shastin

ABSTRACT

The kinetics of thermal decomposition of 2,4-bis(dimethylamino)-6-trinitromethyl-1,3,5-triazine has been studied in melt and in a dilute solution of dinonyl phthalate by manometric and gravimetric methods. The reaction has proven to be self-accelerated. The additives of N-phenylmorpholine significantly have accelerated the decomposition. A conclusion has been drawn that the dimethylamine substituents in the molecule of the initial substance are directly involved in a rate-limiting step of the reaction. Compared to the reaction in the melt, the reaction in a dilute solution has been much slower (which is not typical of the thermal decomposition of nitro compounds). This result is explained by the fact that some of the rate-limiting steps of the process are bimolecular. This is confirmed by the values of the activation parameters for the initial steps of thermal decomposition. More... »

PAGES

632-635

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1990793119040201

DOI

http://dx.doi.org/10.1134/s1990793119040201

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1121454976


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