Ontology type: schema:ScholarlyArticle
2018-12
AUTHORSM. O. Kostenko, K. B. Ustinovich, O. I. Pokrovskiy, O. O. Parenago, N. G. Bazarnova, V. V. Lunin
ABSTRACTThree chiral chromatography stationary phases based on amylose and cellulose were tested for the supercritical fluid chromatography separation of antiasthmatic drug salbutamol enantiomers. A cellulose tris- 3-chloro-4-methylphenylcarbamate stationary phase provided the highest selectivity for this separation. The optimization of mobile phase composition allowed us to maximize the selectivity coefficient and to minimize the peak asymmetry factors. A successful salbutamol enantiomer separation is achieved at moderate modifier fraction (10–15 vol %) in the mobile phase on this column. Amine additives are necessary to suppress peak tailing. Among three tested amines isopropylamine gives the most symmetrical peaks along with the highest enantioselectivity. More... »
PAGES1166-1175
http://scigraph.springernature.com/pub.10.1134/s1990793118070059
DOIhttp://dx.doi.org/10.1134/s1990793118070059
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