Peculiarities of Composition of Hydrocarbon and Heteroatomic Substances Obtained during Conversion of Kashpir Oil Shale in Supercritical Water View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-12

AUTHORS

O. N. Fedyaeva, V. R. Antipenko, A. A. Vostrikov

ABSTRACT

The composition of oily fractions (OFs) formed by the Kashpir oil shale conversion in a flow of water vapor and supercritical water under uniform heating from 300 to 550°C is studied by means of gas-chromatography/ mass-spectrometry, IR, and 1H NMR spectroscopy. The maximum yield of the oil fraction is observed at 360–390°C. Alkanes, alkenes, and alkyl-derivatives of naphthalene and benzothiophene are the major components of the OFs formed below 440°C. A significant predominance of even alkanes and alkenes over their odd homologies is detected above 440°C. The peculiarities in the varying of the content of specific groups and individual polyaromatic substances are discussed. More... »

PAGES

1246-1254

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1990793117080036

DOI

http://dx.doi.org/10.1134/s1990793117080036

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1101374483


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