Structure and reactivity of mechanoactivated Mg (Al)/MoO3 nanocomposites View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-07

AUTHORS

A. N. Streletskii, I. V. Kolbanev, K. Ya. Troshin, A. A. Borisov, A. V. Leonov, S. N. Mudretsova, V. V. Artemov, A. Yu. Dolgoborodov

ABSTRACT

X-ray diffraction and thermal analyses, microscopy, and specific surface area measurements are used to study the formation, structure, and reactivity of mechanoactivated Mg/MoO3 and Al/MoO3 nanocomposites during slow heating (10°C/min). The optimal mechanoactivation dose is determined. The mechanoactivated Mg/MoO3 composite is a dense mixture of two nanosized components with a contact surface of ~8 m2/g (upper estimate). The area of the contact surface between the components of the Al/MoO3 composite is less than 2 m2/g, with the sample consisting of micron-sized aluminum flakes coated with nanoparticles oxide nanoparticles. When heated, the Mg/MoO3 system explodes, with the temperature of explosion being determined by the heating conditions. The minimum temperature of conversion is ~250°C, close to the temperature of autoignition of fuel–air mixtures promoted by these additives. The Al/MoO3 system is characterized by a phased progress of the reaction in the temperature range of 200 to 1000°C. The reasons for the differences in the reactivity of the mixtures are discussed. More... »

PAGES

707-718

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1990793116040114

DOI

http://dx.doi.org/10.1134/s1990793116040114

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1021163627


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