Thermal decomposition of 2,4-diazido-6-trinitromethyl-1,3,5-triazine, 2,4-dimethoxy-6-trinitromethyl-1,3,5-triazine, and 2,4-diazido-6-methoxy-1,3,5-triazine View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-11

AUTHORS

V. V. Nedel’ko, V. V. Zakharov, B. L. Korsounskii, T. S. Larikova, N. V. Chukanov, A. V. Shastin

ABSTRACT

The thermal decomposition of 2,4-diazido-6-trinitromethyl-1,3,5-triazine, 2,4-dimethoxy-6-trinitromethyl-1,3,5-triazine, and 2,4-diazido-6-methoxy-1,3,5-triazine in a melt was studied by differential scanning calorimetry, thermogravimetry, manometry, mass spectrometry, and IR spectroscopy. The kinetics of these reactions was investigated, and the activation parameters were determined. The gaseous products of the decomposition of 6-trinitromethyl-2,4-diazido-1,3,5-triazine were N2, NO, N2O, CO, and CO2 in a molar ratio of 1: 2: 1: 0.6: 1 and pronounced amounts of NO2. A comparison of kinetic data for the compounds under study indicated that the azide groups in 2,4-diazido-6-trinitromethyl-1,3,5-triazine were thermally more stable than the trinitromethyl group. More... »

PAGES

885-889

References to SciGraph publications

  • 2013-03. Thermal decomposition of [1,2,5]Oxadiazolo[3,4-e][1,2,3,4]-Tetrazine-4,6-di-N-Oxide in RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B
  • 2014-09. Energy potential of some triazine derivatives in RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B
  • 2011-02. Tendencies in the development of studies of high explosives in RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B
  • 2011-02. Enthalpy of formation and explosive properties of 5,6-(3,4-furazano)-1,2,3,4-tetrazine-1,3-dioxide in RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B
  • 2011-04. The thermal decomposition of azidopyridines in RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B
  • 2009-09. Mechanical sensitivity of furazano-1,2,3,4-tetrazine-1,3-dioxide in COMBUSTION, EXPLOSION, AND SHOCK WAVES
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    http://scigraph.springernature.com/pub.10.1134/s1990793115060172

    DOI

    http://dx.doi.org/10.1134/s1990793115060172

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