Effect of hydrogen additives on the self-ignition of rich oxygen methane-propane mixtures View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-11

AUTHORS

A. A. Borisov, K. Ya. Troshin, G. I. Skachkov, Yu. A. Kolbanovskii, I. V. Bilera

ABSTRACT

The effect of small hydrogen additives on the ignition of rich oxygen methane-propane mixtures, which imitated associated petroleum gas, was studied at elevated pressures in a static reactor. The experiments showed that the additions of hydrogen increased the ignition temperature of the mixtures by approximately 140 K; that is, they inhibited the ignition of hydrocarbon mixtures at low temperatures. However, on the contrary, the small additions of hydrogen at higher temperatures promoted their ignition. The additions of hydrogen significantly increased the manifestation of a negative temperature coefficient of reaction rate in the ignition of hydrocarbons. A comparison of the experimental data with the results of calculations performed using kinetic programs showed the need for the considerable expansion of a detailed mechanism in the domain of existence of the negative temperature coefficient of the reaction rate of hydrocarbon oxidation. More... »

PAGES

866-869

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1990793114110153

DOI

http://dx.doi.org/10.1134/s1990793114110153

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1019772928


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Moscow Engineering Physics Institute", 
          "id": "https://www.grid.ac/institutes/grid.183446.c", 
          "name": [
            "Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, Russia", 
            "National Research Nuclear University (MEPhI), Kashirskoe sh. 31, 115409, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Borisov", 
        "givenName": "A. A.", 
        "id": "sg:person.016337546241.90", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016337546241.90"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Moscow Engineering Physics Institute", 
          "id": "https://www.grid.ac/institutes/grid.183446.c", 
          "name": [
            "Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, Russia", 
            "National Research Nuclear University (MEPhI), Kashirskoe sh. 31, 115409, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Troshin", 
        "givenName": "K. Ya.", 
        "id": "sg:person.015655434623.18", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015655434623.18"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Skachkov", 
        "givenName": "G. I.", 
        "id": "sg:person.012332521626.60", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012332521626.60"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kolbanovskii", 
        "givenName": "Yu. A.", 
        "id": "sg:person.012671516167.92", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012671516167.92"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bilera", 
        "givenName": "I. V.", 
        "id": "sg:person.012371611264.16", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012371611264.16"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1134/s1990793113050102", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019033617", 
          "https://doi.org/10.1134/s1990793113050102"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0965544110050038", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022444352", 
          "https://doi.org/10.1134/s0965544110050038"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0965544110050038", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022444352", 
          "https://doi.org/10.1134/s0965544110050038"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ijhydene.2009.03.058", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051582821"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1063/1.1748524", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057810668"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2014-11", 
    "datePublishedReg": "2014-11-01", 
    "description": "The effect of small hydrogen additives on the ignition of rich oxygen methane-propane mixtures, which imitated associated petroleum gas, was studied at elevated pressures in a static reactor. The experiments showed that the additions of hydrogen increased the ignition temperature of the mixtures by approximately 140 K; that is, they inhibited the ignition of hydrocarbon mixtures at low temperatures. However, on the contrary, the small additions of hydrogen at higher temperatures promoted their ignition. The additions of hydrogen significantly increased the manifestation of a negative temperature coefficient of reaction rate in the ignition of hydrocarbons. A comparison of the experimental data with the results of calculations performed using kinetic programs showed the need for the considerable expansion of a detailed mechanism in the domain of existence of the negative temperature coefficient of the reaction rate of hydrocarbon oxidation.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s1990793114110153", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136550", 
        "issn": [
          "1990-7931", 
          "1990-7923"
        ], 
        "name": "Russian Journal of Physical Chemistry B", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "8"
      }
    ], 
    "name": "Effect of hydrogen additives on the self-ignition of rich oxygen methane-propane mixtures", 
    "pagination": "866-869", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "5e3595ead5fc63d580f6344d4b8500aa71f02460abdc3dd981d0bab6112ce461"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1990793114110153"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1019772928"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1990793114110153", 
      "https://app.dimensions.ai/details/publication/pub.1019772928"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T14:15", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8660_00000536.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134%2FS1990793114110153"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1990793114110153'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1990793114110153'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1990793114110153'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1990793114110153'


 

This table displays all metadata directly associated to this object as RDF triples.

108 TRIPLES      21 PREDICATES      31 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1990793114110153 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N527ce5b5998d4498ad65496d1ea7586c
4 schema:citation sg:pub.10.1134/s0965544110050038
5 sg:pub.10.1134/s1990793113050102
6 https://doi.org/10.1016/j.ijhydene.2009.03.058
7 https://doi.org/10.1063/1.1748524
8 schema:datePublished 2014-11
9 schema:datePublishedReg 2014-11-01
10 schema:description The effect of small hydrogen additives on the ignition of rich oxygen methane-propane mixtures, which imitated associated petroleum gas, was studied at elevated pressures in a static reactor. The experiments showed that the additions of hydrogen increased the ignition temperature of the mixtures by approximately 140 K; that is, they inhibited the ignition of hydrocarbon mixtures at low temperatures. However, on the contrary, the small additions of hydrogen at higher temperatures promoted their ignition. The additions of hydrogen significantly increased the manifestation of a negative temperature coefficient of reaction rate in the ignition of hydrocarbons. A comparison of the experimental data with the results of calculations performed using kinetic programs showed the need for the considerable expansion of a detailed mechanism in the domain of existence of the negative temperature coefficient of the reaction rate of hydrocarbon oxidation.
11 schema:genre research_article
12 schema:inLanguage en
13 schema:isAccessibleForFree false
14 schema:isPartOf Nd710dc6bd12b4ca4a927b96e27550313
15 Ne4ef224b775e46f5b2301bc68dcb1165
16 sg:journal.1136550
17 schema:name Effect of hydrogen additives on the self-ignition of rich oxygen methane-propane mixtures
18 schema:pagination 866-869
19 schema:productId N84e7cf8d1e7140e6ae14317498a7850a
20 Nd3bac079385049c1a60941088372edd6
21 Nfaac6b2a100e4bb5b3b633675e29ffd7
22 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019772928
23 https://doi.org/10.1134/s1990793114110153
24 schema:sdDatePublished 2019-04-10T14:15
25 schema:sdLicense https://scigraph.springernature.com/explorer/license/
26 schema:sdPublisher Na8ea9286401e4f989a616ed5a741bce4
27 schema:url http://link.springer.com/10.1134%2FS1990793114110153
28 sgo:license sg:explorer/license/
29 sgo:sdDataset articles
30 rdf:type schema:ScholarlyArticle
31 N527ce5b5998d4498ad65496d1ea7586c rdf:first sg:person.016337546241.90
32 rdf:rest Nc5f2f376254a4f0180669f15752b0960
33 N84e7cf8d1e7140e6ae14317498a7850a schema:name doi
34 schema:value 10.1134/s1990793114110153
35 rdf:type schema:PropertyValue
36 N9458adc3a5d84d15baa65a392ead0bf9 rdf:first sg:person.012332521626.60
37 rdf:rest Na642a7561b1a4a688d0a8463a4e88fc2
38 Na642a7561b1a4a688d0a8463a4e88fc2 rdf:first sg:person.012671516167.92
39 rdf:rest Nb6ef8d384967428e8eba2b88f3ba7297
40 Na8ea9286401e4f989a616ed5a741bce4 schema:name Springer Nature - SN SciGraph project
41 rdf:type schema:Organization
42 Nb6ef8d384967428e8eba2b88f3ba7297 rdf:first sg:person.012371611264.16
43 rdf:rest rdf:nil
44 Nc5f2f376254a4f0180669f15752b0960 rdf:first sg:person.015655434623.18
45 rdf:rest N9458adc3a5d84d15baa65a392ead0bf9
46 Nd3bac079385049c1a60941088372edd6 schema:name dimensions_id
47 schema:value pub.1019772928
48 rdf:type schema:PropertyValue
49 Nd710dc6bd12b4ca4a927b96e27550313 schema:volumeNumber 8
50 rdf:type schema:PublicationVolume
51 Ne4ef224b775e46f5b2301bc68dcb1165 schema:issueNumber 6
52 rdf:type schema:PublicationIssue
53 Nfaac6b2a100e4bb5b3b633675e29ffd7 schema:name readcube_id
54 schema:value 5e3595ead5fc63d580f6344d4b8500aa71f02460abdc3dd981d0bab6112ce461
55 rdf:type schema:PropertyValue
56 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
57 schema:name Chemical Sciences
58 rdf:type schema:DefinedTerm
59 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
60 schema:name Physical Chemistry (incl. Structural)
61 rdf:type schema:DefinedTerm
62 sg:journal.1136550 schema:issn 1990-7923
63 1990-7931
64 schema:name Russian Journal of Physical Chemistry B
65 rdf:type schema:Periodical
66 sg:person.012332521626.60 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
67 schema:familyName Skachkov
68 schema:givenName G. I.
69 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012332521626.60
70 rdf:type schema:Person
71 sg:person.012371611264.16 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
72 schema:familyName Bilera
73 schema:givenName I. V.
74 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012371611264.16
75 rdf:type schema:Person
76 sg:person.012671516167.92 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
77 schema:familyName Kolbanovskii
78 schema:givenName Yu. A.
79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012671516167.92
80 rdf:type schema:Person
81 sg:person.015655434623.18 schema:affiliation https://www.grid.ac/institutes/grid.183446.c
82 schema:familyName Troshin
83 schema:givenName K. Ya.
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015655434623.18
85 rdf:type schema:Person
86 sg:person.016337546241.90 schema:affiliation https://www.grid.ac/institutes/grid.183446.c
87 schema:familyName Borisov
88 schema:givenName A. A.
89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016337546241.90
90 rdf:type schema:Person
91 sg:pub.10.1134/s0965544110050038 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022444352
92 https://doi.org/10.1134/s0965544110050038
93 rdf:type schema:CreativeWork
94 sg:pub.10.1134/s1990793113050102 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019033617
95 https://doi.org/10.1134/s1990793113050102
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1016/j.ijhydene.2009.03.058 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051582821
98 rdf:type schema:CreativeWork
99 https://doi.org/10.1063/1.1748524 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057810668
100 rdf:type schema:CreativeWork
101 https://www.grid.ac/institutes/grid.183446.c schema:alternateName Moscow Engineering Physics Institute
102 schema:name National Research Nuclear University (MEPhI), Kashirskoe sh. 31, 115409, Moscow, Russia
103 Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, Russia
104 rdf:type schema:Organization
105 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
106 schema:name Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, Russia
107 Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, Russia
108 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...