Dissolution of oxide nuclear fuel in subacidic iron(III) nitrate solutions and extraction of uranium from it with tributyl phosphate-containing supercritical ... View Full Text


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Article Info

DATE

2014-12

AUTHORS

M. D. Samsonov, T. I. Trofimov, S. E. Vinokurov, Yu. M. Kulyako, B. F. Myasoedov

ABSTRACT

The solubility of the uranyl nitrate complex with tributyl phosphate (TBP) in liquid and supercritical carbon dioxide (SC-CO2) has been measured as a function of temperature and pressure. This complex is formed upon the dissolution of uranium dioxide in the two-phase system consisting of aqueous iron(III) nitrate and TBP-saturated liquid or supercritical CO2. The kinetics of the dissolution of ceramic UO2 in such a two-phase solvent is studied. It has been shown that uranium can be extracted in the presence of TBP-containing supercritical CO2 via the dissolution of spent oxide nuclear fuel in subacidic iron(III) nitrate solutions with the simultaneous extraction of the uranium complex into the TBP-SC-CO2 phase. More... »

PAGES

939-943

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1990793114070124

DOI

http://dx.doi.org/10.1134/s1990793114070124

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1042586795


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