Kinetics of reversible polymorphic transitions in high-energy compounds. Phase transformations in octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine View Full Text


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Article Info

DATE

2014-09

AUTHORS

N. V. Chukanov, V. V. Zakharov, S. A. Vozchikova, A. D. Chervonnyi, B. L. Korsounskii

ABSTRACT

The kinetics of reversible phase transitions (PTs) in various polymorphs (α, β, γ, δ, and ɛ) of polycrystalline octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) is investigated by means of differential isothermal and scanning calorimetry. The rate of the β → δ PT is limited by the nucleation process occurring during the induction period. In a general case, the distribution density for the induction times is a superposition of continuous and discrete functions. The reverse δ → β PT obeys the first-order kinetic law. The effects of mechanical exposure on the kinetics and the PT products of the different polymorphs of HMX is investigated by FTIR spectroscopy. More... »

PAGES

641-650

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1990793114050133

DOI

http://dx.doi.org/10.1134/s1990793114050133

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1044155967


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