Thermal decomposition of [1,2,5]Oxadiazolo[3,4-e][1,2,3,4]-Tetrazine-4,6-di-N-Oxide View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-03

AUTHORS

V. V. Nedel’ko, V. V. Zakharov, B. L. Korsunskii, T. S. Larikova, N. V. Chukanov, M. S. Kiselev, P. I. Kalmykov

ABSTRACT

The thermal decomposition of [1,2,5]oxadiazolo[3,4-e][1,2,3,4]-tetrazine-4,6-di-N-oxide (furazano tetrazine dioxide, FTDO) in the solid state, melt, and dinonyl phthalate solution is studied. The kinetic and thermodynamic parameters of the process are determined. These results enable to estimate the thermal stability of FTDO. The composition of the gaseous reaction products and the elemental composition of the condensed product are determined. On the basis of kinetic, analytical, and spectral data, the mechanism of the process, including the formation of the N-nitrosofurazanoaziridine intermediate, is discussed. More... »

PAGES

113-117

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1990793113020048

DOI

http://dx.doi.org/10.1134/s1990793113020048

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1028400078


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