Synthesis, Molecular, and Gas-Transport Properties of Homopolymers Based on 5-Ethylidene-2-norbornene and 5-Vinyl-2-norbornene View Full Text


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Article Info

DATE

2019-09

AUTHORS

E. V. Bermesheva, A. I. Wozniak, I. L. Borisov, N. P. Yevlampieva, O. S. Vezo, G. O. Karpov, M. V. Bermeshev, A. F. Asachenko, M. A. Topchiy, P. S. Gribanov, M. S. Nechaev, V. V. Volkov, E. Sh. Finkelshtein

ABSTRACT

—Using the commercial derivative of norbornene—5-ethylidene-2-norbornene—a series of three isomeric homopolymers with different structure of the backbone is synthesized, and the effect of the chain structure on the gas-transport behavior of polynorbornenes is studied. The gas-transport characteristics of the polymers are presented together with data on the conformation properties of molecules of addition and metathesis polynorbornenes. The effect of the structure of side substituents on the equilibrium rigidity of addition polynorbornenes is confirmed by the example of poly(5-ethylidene-2-norbornene) and poly(5-vinyl-2-norbornene). More... »

PAGES

86-101

References to SciGraph publications

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  • 2018-07-02. Metathesis and additive poly(tricyclononenes) with geminal trimethylsilyl side groups: chain rigidity, molecular and thin film properties in JOURNAL OF POLYMER RESEARCH
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  • 2018-03-16. Molecular Properties of Additive Poly(bis(trimethylsilyl)tricyclonones) with Vicinal and Geminal Side Substituents in POLYMER SCIENCE SERIES A
  • 2018-04. Addition Polymerization of 5-Ethylidene-2-Norbornene in the Presence of Pd N-Heterocyclic Carbene Complexes in DOKLADY CHEMISTRY
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  • 2017-07-25. The equilibrium and kinetic rigidity of additive poly(trimethylsilyltricyclononenes) with one and two Si(CH3)3 groups in monomer unit in POLYMER SCIENCE SERIES A
  • 2016-11. Synthesis and gas separation properties of metathesis poly(5-ethylidene-2-norbornene) in PETROLEUM CHEMISTRY
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  • 2011-08. Copolymers of norbornene and its derivatives with acrylates—Promising materials for optoelectronics in DOKLADY CHEMISTRY
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