Coatings and surfactants based on oligovinylsiloxanes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-05

AUTHORS

G. D. Markova, V. A. Vasnev, B. A. Izmailov, I. A. Gritskova, A. V. Naumkin, S. V. Dvoryak, A. S. Ivanov

ABSTRACT

Silicate glass and cotton fabric are hydrophobized via treatment of their surface by vinyltriethoxysilane and oligovinylsiloxane. The data of electron microscopy for chemical analysis and the values of contact angles suggest that the hydrophobicity of the surface layer develops via the polymerization of vinyl groups. The arrangement of vinyl groups in neighboring units in oligovinylsiloxane is favorable for formation of a more uniform solid coating with enhanced hydrophobicity. The use of oligovinylsiloxane and its derivatives with amino and carboxyl groups as surfactants in the heterophase polymerization of styrene makes it possible to obtain stable suspensions with a narrow particle size distribution. More... »

PAGES

248-256

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1560090417030125

DOI

http://dx.doi.org/10.1134/s1560090417030125

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1090300149


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Macromolecular and Materials Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Markova", 
        "givenName": "G. D.", 
        "id": "sg:person.016434044347.74", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016434044347.74"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vasnev", 
        "givenName": "V. A.", 
        "id": "sg:person.015033061467.18", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015033061467.18"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Izmailov", 
        "givenName": "B. A.", 
        "id": "sg:person.012430437711.81", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012430437711.81"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Moscow Technological University, pr. Vernadskogo 86, 119571, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.466477.0", 
          "name": [
            "Moscow Technological University, pr. Vernadskogo 86, 119571, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gritskova", 
        "givenName": "I. A.", 
        "id": "sg:person.016001635751.75", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016001635751.75"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Naumkin", 
        "givenName": "A. V.", 
        "id": "sg:person.013342122543.92", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013342122543.92"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dvoryak", 
        "givenName": "S. V.", 
        "id": "sg:person.015342102063.97", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015342102063.97"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ivanov", 
        "givenName": "A. S.", 
        "id": "sg:person.016137462463.05", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016137462463.05"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1134/s1560090415060068", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006083085", 
          "https://doi.org/10.1134/s1560090415060068"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s002890050312", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051161854", 
          "https://doi.org/10.1007/s002890050312"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s002890050549", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1045496687", 
          "https://doi.org/10.1007/s002890050549"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2017-05", 
    "datePublishedReg": "2017-05-01", 
    "description": "Silicate glass and cotton fabric are hydrophobized via treatment of their surface by vinyltriethoxysilane and oligovinylsiloxane. The data of electron microscopy for chemical analysis and the values of contact angles suggest that the hydrophobicity of the surface layer develops via the polymerization of vinyl groups. The arrangement of vinyl groups in neighboring units in oligovinylsiloxane is favorable for formation of a more uniform solid coating with enhanced hydrophobicity. The use of oligovinylsiloxane and its derivatives with amino and carboxyl groups as surfactants in the heterophase polymerization of styrene makes it possible to obtain stable suspensions with a narrow particle size distribution.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s1560090417030125", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1400109", 
        "issn": [
          "1560-0904", 
          "1555-6123"
        ], 
        "name": "Polymer Science, Series B", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "59"
      }
    ], 
    "keywords": [
      "vinyl groups", 
      "narrow particle size distribution", 
      "heterophase polymerization", 
      "solid coating", 
      "enhanced hydrophobicity", 
      "carboxyl groups", 
      "stable suspension", 
      "contact angle", 
      "chemical analysis", 
      "cotton fabrics", 
      "polymerization", 
      "electron microscopy", 
      "surfactants", 
      "particle size distribution", 
      "hydrophobicity", 
      "silicate glasses", 
      "size distribution", 
      "coatings", 
      "surface layer", 
      "vinyltriethoxysilane", 
      "oligovinylsiloxanes", 
      "styrene", 
      "derivatives", 
      "amino", 
      "microscopy", 
      "surface", 
      "glass", 
      "formation", 
      "suspension", 
      "layer", 
      "group", 
      "arrangement", 
      "fabric", 
      "units", 
      "angle", 
      "values", 
      "analysis", 
      "distribution", 
      "use", 
      "treatment", 
      "data"
    ], 
    "name": "Coatings and surfactants based on oligovinylsiloxanes", 
    "pagination": "248-256", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1090300149"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1560090417030125"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1560090417030125", 
      "https://app.dimensions.ai/details/publication/pub.1090300149"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-10-01T06:43", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221001/entities/gbq_results/article/article_728.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s1560090417030125"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1560090417030125'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1560090417030125'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1560090417030125'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1560090417030125'


 

This table displays all metadata directly associated to this object as RDF triples.

162 TRIPLES      21 PREDICATES      70 URIs      58 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1560090417030125 schema:about anzsrc-for:03
2 anzsrc-for:0303
3 anzsrc-for:0306
4 schema:author N6f7b6093e1844c348723577cb9d9d2ae
5 schema:citation sg:pub.10.1007/s002890050312
6 sg:pub.10.1007/s002890050549
7 sg:pub.10.1134/s1560090415060068
8 schema:datePublished 2017-05
9 schema:datePublishedReg 2017-05-01
10 schema:description Silicate glass and cotton fabric are hydrophobized via treatment of their surface by vinyltriethoxysilane and oligovinylsiloxane. The data of electron microscopy for chemical analysis and the values of contact angles suggest that the hydrophobicity of the surface layer develops via the polymerization of vinyl groups. The arrangement of vinyl groups in neighboring units in oligovinylsiloxane is favorable for formation of a more uniform solid coating with enhanced hydrophobicity. The use of oligovinylsiloxane and its derivatives with amino and carboxyl groups as surfactants in the heterophase polymerization of styrene makes it possible to obtain stable suspensions with a narrow particle size distribution.
11 schema:genre article
12 schema:isAccessibleForFree false
13 schema:isPartOf N09054f74dba24c66bc0f887e5850391d
14 N586ff8563c4d43efa4589273a5f66d4b
15 sg:journal.1400109
16 schema:keywords amino
17 analysis
18 angle
19 arrangement
20 carboxyl groups
21 chemical analysis
22 coatings
23 contact angle
24 cotton fabrics
25 data
26 derivatives
27 distribution
28 electron microscopy
29 enhanced hydrophobicity
30 fabric
31 formation
32 glass
33 group
34 heterophase polymerization
35 hydrophobicity
36 layer
37 microscopy
38 narrow particle size distribution
39 oligovinylsiloxanes
40 particle size distribution
41 polymerization
42 silicate glasses
43 size distribution
44 solid coating
45 stable suspension
46 styrene
47 surface
48 surface layer
49 surfactants
50 suspension
51 treatment
52 units
53 use
54 values
55 vinyl groups
56 vinyltriethoxysilane
57 schema:name Coatings and surfactants based on oligovinylsiloxanes
58 schema:pagination 248-256
59 schema:productId N63e865e0d7314209957c41c6d8c12600
60 N94a2ac085ead41bd82b98036b0118bbb
61 schema:sameAs https://app.dimensions.ai/details/publication/pub.1090300149
62 https://doi.org/10.1134/s1560090417030125
63 schema:sdDatePublished 2022-10-01T06:43
64 schema:sdLicense https://scigraph.springernature.com/explorer/license/
65 schema:sdPublisher N1c8992dfe56247ff99e83c8810051432
66 schema:url https://doi.org/10.1134/s1560090417030125
67 sgo:license sg:explorer/license/
68 sgo:sdDataset articles
69 rdf:type schema:ScholarlyArticle
70 N09054f74dba24c66bc0f887e5850391d schema:issueNumber 3
71 rdf:type schema:PublicationIssue
72 N1c8992dfe56247ff99e83c8810051432 schema:name Springer Nature - SN SciGraph project
73 rdf:type schema:Organization
74 N36e23204faf74ec29fb1d7f69a6e0996 rdf:first sg:person.012430437711.81
75 rdf:rest Nf21fd44cc58e4ffebc79287b167eb1a7
76 N586ff8563c4d43efa4589273a5f66d4b schema:volumeNumber 59
77 rdf:type schema:PublicationVolume
78 N63e865e0d7314209957c41c6d8c12600 schema:name doi
79 schema:value 10.1134/s1560090417030125
80 rdf:type schema:PropertyValue
81 N6f7b6093e1844c348723577cb9d9d2ae rdf:first sg:person.016434044347.74
82 rdf:rest Nd24f637c46d848f386a465585c826868
83 N94a2ac085ead41bd82b98036b0118bbb schema:name dimensions_id
84 schema:value pub.1090300149
85 rdf:type schema:PropertyValue
86 Nd24f637c46d848f386a465585c826868 rdf:first sg:person.015033061467.18
87 rdf:rest N36e23204faf74ec29fb1d7f69a6e0996
88 Nd3539140dcbc434e8ecb916becd5d19e rdf:first sg:person.015342102063.97
89 rdf:rest Nf797bb8508d04dbb9ec058604309646d
90 Neee5621708624dbe9d7811156caaaab0 rdf:first sg:person.013342122543.92
91 rdf:rest Nd3539140dcbc434e8ecb916becd5d19e
92 Nf21fd44cc58e4ffebc79287b167eb1a7 rdf:first sg:person.016001635751.75
93 rdf:rest Neee5621708624dbe9d7811156caaaab0
94 Nf797bb8508d04dbb9ec058604309646d rdf:first sg:person.016137462463.05
95 rdf:rest rdf:nil
96 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
97 schema:name Chemical Sciences
98 rdf:type schema:DefinedTerm
99 anzsrc-for:0303 schema:inDefinedTermSet anzsrc-for:
100 schema:name Macromolecular and Materials Chemistry
101 rdf:type schema:DefinedTerm
102 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
103 schema:name Physical Chemistry (incl. Structural)
104 rdf:type schema:DefinedTerm
105 sg:journal.1400109 schema:issn 1555-6123
106 1560-0904
107 schema:name Polymer Science, Series B
108 schema:publisher Pleiades Publishing
109 rdf:type schema:Periodical
110 sg:person.012430437711.81 schema:affiliation grid-institutes:grid.431939.5
111 schema:familyName Izmailov
112 schema:givenName B. A.
113 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012430437711.81
114 rdf:type schema:Person
115 sg:person.013342122543.92 schema:affiliation grid-institutes:grid.431939.5
116 schema:familyName Naumkin
117 schema:givenName A. V.
118 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013342122543.92
119 rdf:type schema:Person
120 sg:person.015033061467.18 schema:affiliation grid-institutes:grid.431939.5
121 schema:familyName Vasnev
122 schema:givenName V. A.
123 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015033061467.18
124 rdf:type schema:Person
125 sg:person.015342102063.97 schema:affiliation grid-institutes:grid.14476.30
126 schema:familyName Dvoryak
127 schema:givenName S. V.
128 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015342102063.97
129 rdf:type schema:Person
130 sg:person.016001635751.75 schema:affiliation grid-institutes:grid.466477.0
131 schema:familyName Gritskova
132 schema:givenName I. A.
133 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016001635751.75
134 rdf:type schema:Person
135 sg:person.016137462463.05 schema:affiliation grid-institutes:grid.14476.30
136 schema:familyName Ivanov
137 schema:givenName A. S.
138 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016137462463.05
139 rdf:type schema:Person
140 sg:person.016434044347.74 schema:affiliation grid-institutes:grid.431939.5
141 schema:familyName Markova
142 schema:givenName G. D.
143 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016434044347.74
144 rdf:type schema:Person
145 sg:pub.10.1007/s002890050312 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051161854
146 https://doi.org/10.1007/s002890050312
147 rdf:type schema:CreativeWork
148 sg:pub.10.1007/s002890050549 schema:sameAs https://app.dimensions.ai/details/publication/pub.1045496687
149 https://doi.org/10.1007/s002890050549
150 rdf:type schema:CreativeWork
151 sg:pub.10.1134/s1560090415060068 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006083085
152 https://doi.org/10.1134/s1560090415060068
153 rdf:type schema:CreativeWork
154 grid-institutes:grid.14476.30 schema:alternateName Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia
155 schema:name Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia
156 rdf:type schema:Organization
157 grid-institutes:grid.431939.5 schema:alternateName Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia
158 schema:name Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia
159 rdf:type schema:Organization
160 grid-institutes:grid.466477.0 schema:alternateName Moscow Technological University, pr. Vernadskogo 86, 119571, Moscow, Russia
161 schema:name Moscow Technological University, pr. Vernadskogo 86, 119571, Moscow, Russia
162 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...