Homo- and copoly(arylene ether ketones) with side hydroxyl groups View Full Text


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Article Info

DATE

2009-02

AUTHORS

A. N. Ryabev, K. I. Donetskii, V. V. Shaposhnikova, S. N. Salazkin, L. V. Dubrovina, T. P. Bragina, A. S. Tkachenko

ABSTRACT

The polycondensation of 2-β-oxyethyl-3,3-bis(4-oxyphenyl)phthalimidine with 4,4′-difluorobenzophenone proceeding via the nucleophilic substitution of the activated halogen atom in aryl halide has been studied. Conditions ensuring formation of noncrosslinked high-molecular-mass homo- and copoly(arylene ether ketones) containing side alcoholic hydroxyl groups (4,4′-difluorobenzophenone: a mixture of bisphenols: K2CO3: Na2CO3 = 1: 1: 1: 0.05) have been established. The polymers have Mw = (20–88.7) × 103 and show good solubility in organic solvents; their onset temperatures of softening are in the range 195–250°C. Polymer films cast from solution are characterized by a breaking strength of 78–109 MPa. More... »

PAGES

27-32

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1560090409010047

DOI

http://dx.doi.org/10.1134/s1560090409010047

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1027753452


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