Phase composition and structure of molybdenum-, copper-, and cesium-containing sodium aluminophosphate glassy materials for immobilization of high level wastes of ... View Full Text


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Article Info

DATE

2014-09

AUTHORS

M. B. Remizov, E. A. Belanova, S. V. Stefanovsky, B. F. Myasoedov, B. S. Nikonov

ABSTRACT

Molybdenum-, copper-, and cesium-containing glass based on aluminophosphate designed to immobilize high-active wastes (HAWs), which are formed at the reprocessing of spent nuclear fuel (SNF) from Atom Peaceful Big (AMB) nuclear reactor, have been synthesized and studied by means of the X-ray diffraction and electron-microscopy methods. After quenching the melts, glass, which partially crystallizes at annealing, is formed. The introduction of magnesium oxide in aluminophosphate glass increases its crystallization resistance; and molybdenum oxide, decreases. The samples crystallize after heat treatment with the formation of aluminum and sodium-aluminum orthophosphates and solid solution of the (Na,Cs)3−3xAlxPO4 composition. More... »

PAGES

534-542

References to SciGraph publications

  • 1995-01. Les systemes binaires AlPO4−M3PO4 (M=Li, Na, K) in JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
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    http://scigraph.springernature.com/pub.10.1134/s1087659614050149

    DOI

    http://dx.doi.org/10.1134/s1087659614050149

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